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The order of stability of the alkenes ...

The order of stability of the alkenes
`underset(I)(R_(2)C=CR_(2)') underset(II)(R_(2)C=CHR), underset(III)(R_(2)C=CH_(2)')underset(IV)
(RCH=CHR,) "and" underset(V)(RCH=CH_(2))`
is -

A

`IgtIIgtIIIgtIVgtV`

B

`I=IIgtIIIgtIVgtV`

C

`IIgtIIgtIVgtIIIgtV`

D

`VgtIVgtIIIgtIgtII`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of stability of the given alkenes based on the number of alpha hydrogens and hyperconjugation, we will analyze each alkene step by step. ### Step-by-Step Solution: 1. **Identify the Structures of the Alkenes**: - Alkene I: \( R_2C=CR_2' \) - Alkene II: \( R_2C=CHR \) - Alkene III: \( R_2C=CH_2 \) - Alkene IV: \( RCH=CHR \) - Alkene V: \( RCH=CH_2 \) 2. **Assume R as Methyl (CH₃)**: To simplify the calculation, we will assume that R is a methyl group (CH₃) for each alkene. 3. **Count Alpha Hydrogens**: - **Alkene I**: \( R_2C=CR_2' \) (Assuming R = CH₃) - Structure: \( (CH_3)_{2}C=CH_{2} \) - Alpha Hydrogens: 12 (from both \( CH_3 \) groups) - **Alkene II**: \( R_2C=CHR \) - Structure: \( (CH_3)_{2}C=CH_{3} \) - Alpha Hydrogens: 9 (from two \( CH_3 \) groups and one \( CH \) group) - **Alkene III**: \( R_2C=CH_2 \) - Structure: \( (CH_3)_{2}C=CH_{2} \) - Alpha Hydrogens: 6 (from two \( CH_3 \) groups) - **Alkene IV**: \( RCH=CHR \) - Structure: \( CH_3CH=CH_{3} \) - Alpha Hydrogens: 6 (from two \( CH_3 \) groups) - **Alkene V**: \( RCH=CH_2 \) - Structure: \( CH_3CH=CH_{2} \) - Alpha Hydrogens: 3 (from one \( CH_3 \) group) 4. **Order of Stability**: Based on the number of alpha hydrogens: - Alkene I: 12 alpha hydrogens (most stable) - Alkene II: 9 alpha hydrogens - Alkene III: 6 alpha hydrogens - Alkene IV: 6 alpha hydrogens - Alkene V: 3 alpha hydrogens (least stable) 5. **Final Order**: The order of stability from most stable to least stable is: - I > II > III = IV > V ### Conclusion: Thus, the order of stability of the alkenes is: **I > II > III = IV > V**
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The order of stability of the alkenes underset(I)(R_(2)C=CR_(2)') underset(II)(R_(2)C=CHE) underset(III)(R_(2)C=CH_(2)')underset(IV)(RCH=CHR,) "and" underset(V)(RCH=CH_(2)) is -

The bond dissociation energies of the following underset(I)(CH_(3)-H) underset(II)(CH_(3)CH_(2)-H) underset(III)(CH_(2)=CH-CH_(2)-H) underset(IV)(C_(6)H_(5)-H) vary in the order :

Arrange the following molecules from most to least polar. underset("I")(CH_(4))underset("II")(CF_(2)Cl_(2))underset("III")(CF_(2)H_(2))underset("IV")("CCl"_(4))underset("V")(CH_(2)Cl_(2))

Give the IUPAC name CH_(3)-underset(C_(2)H_(5))underset(|)(CH)-CH_(2)=underset(C_(2)H_(5))underset(|)(CH)-CH_(3)

Give its IUPAC name. CH_(3)-underset(C_(2)H_(5))underset(|)(C )H-CH_(2)-underset(C_(2)H_(5))underset(|)(C )H-CH_(3)

Arrange following compounds in decreasing order of their dipole moment. underset("I")(CH_(3)-CH_(2)-NO_(2))" "underset("II")(CH_(3)-CH_(2)-NH_(2))" "underset("III")(CH_(3)-CH_(2)-F)" underset("IV")(CH_(3)-CH_(2)-C-=N)

What is the correct order of decreasing stability of the following cations? underset(I)(CH_(3)-overset(+)(C)H-CH_(3))" "underset(II)(CH_(3)-overset(+)(C)H-OCH_(3)) underset(III)(CH_(3)-overset(+)(C)H-CH_(2)-OCH_(3))

IUPAC Name of : CH_(2)=CH-underset(CH_(2))underset(||)(C)-C-=CH

Determine the stability order of given carbocations : underset(i.)(CH_(3)-CH_(2)^(+)) underset(ii.)(CH_(2)=CH^(+))

ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-1
  1. Which of the following has the smallest heat of hydrogenation per mole...

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  2. The intermediate during the addition of HCl to propene n presence of p...

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  3. The order of stability of the alkenes underset(I)(R(2)C=CR(2)') unde...

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  4. Which of the following will not react with an ammonical silver nitrate...

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  5. The correct order of reactivity towards the electrophillic substituion...

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  6. Which of the following order is correct for the decreasing reactivity ...

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  7. Electrophile overset(o+)NO(2) attacks the following : In which ca...

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  8. The most deactivating group for electrophilic substitution reaction in...

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  9. Which of the following is the most reactive towards ring nitration ?

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  10. The order decreasing reactivity towards an electrophilic reagent, for ...

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  11. Increasing order of the following for electrophilic substitution react...

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  12. Among the compounds the order of decreasing reactivity towards electro...

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  13. Choose the most reactive among the following compound :

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  14. Write the structures of possible isomers of dichlorobenzene.

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  15. The major product form by the monobromination of phenyl benzoate is

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  16. The major product formed in the reaction is:

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  17. The electrophilic aromatic substitution of a compound C(6)H(5)Y produc...

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  18. Which of the following is an o-, p-directing but deactivating substitu...

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  19. The major product formed in the reaction is :

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  20. The dipole moment of chlorobenzene is 1.6Dm The expected dipole moment...

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