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One mole of a symmetrical alkene on ozon...

One mole of a symmetrical alkene on ozonolysis gives two moles of
an aldehyde having a molecular mass of 30u. The alkene is:

A

ethene

B

propene

C

`1-`butene

D

`2-`butene

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine which symmetrical alkene, when subjected to ozonolysis, yields two moles of an aldehyde with a molecular mass of 30u. ### Step-by-Step Solution: 1. **Understanding Ozonolysis**: Ozonolysis is a reaction where alkenes react with ozone (O3) to form ozonides, which can be further reduced to yield aldehydes or ketones. The products depend on the structure of the alkene. 2. **Identifying Symmetrical Alkenes**: The problem specifies a symmetrical alkene. The common symmetrical alkenes include ethene (C2H4) and 2-butene (C4H8). We will analyze these two options. 3. **Analyzing Ethene (C2H4)**: - The structure of ethene is H2C=CH2. - Upon ozonolysis, ethene forms an ozonide which, when reduced (using Zn/H2O), yields two moles of formaldehyde (HCHO). - The molecular mass of formaldehyde (HCHO) is calculated as follows: - H: 1u (2 H atoms) = 2u - C: 12u (1 C atom) = 12u - O: 16u (1 O atom) = 16u - Total = 2u + 12u + 16u = 30u 4. **Analyzing 2-Butene (C4H8)**: - The structure of 2-butene is CH3-CH=CH-CH3. - Upon ozonolysis, 2-butene forms an ozonide which, when reduced, yields two moles of acetaldehyde (CH3CHO). - The molecular mass of acetaldehyde (CH3CHO) is calculated as follows: - H: 1u (4 H atoms) = 4u - C: 12u (2 C atoms) = 24u - O: 16u (1 O atom) = 16u - Total = 4u + 24u + 16u = 44u 5. **Conclusion**: Since the molecular mass of the aldehyde produced from 2-butene is 44u, it does not match the requirement of 30u. Therefore, the only alkene that fits the criteria is ethene. ### Final Answer: The symmetrical alkene is **Ethene (C2H4)**.
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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-5(A)
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  4. The alkene formed as a major product in the above elimination reaction...

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  5. Reaction of trans-2-phenyl-1-bromocyclopentane on reaction with alcoho...

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  6. Phenyl magnesium bromide reacts with methanol to give

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  7. Which of the following reactions will yield 2, 2-dibromopropane ?

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  8. In the following sequence of reactions, the alkene affords the compoun...

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  9. The hydrocarbon which can react with sodium in liquid ammonia is : 1....

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  10. The treatment of CH3MgX with CH3C-=C-H produces

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  11. The main product of the following reaction is : PhCH(2)CH(OH)CH(CH(...

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  12. One mole of a symmetrical alkene on ozonolysis gives two moles of an...

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  13. Ozonolysis of an organic compound gives formaldehyde as one of product...

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  14. Ozonolysis of an organic compound (A) produces acetone and acetaldehyd...

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  15. 2-Hexyne gives trans-2-hexene on treatment with :

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  16. In the given transformation, which of the following is the most approp...

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  17. In the reaction CH(3)COOH overset(LiAIH(4))rarr A overset(PCl(g))rar...

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  18. Which compound will yield 5-keto -2 methyl hexanal upon treatment with...

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  19. The gas evolved on heating CH(3)MgBr in methanol is:

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  20. Bouveault Blanc reduction.

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