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Give the structures of (A),(B) and (C)(e...

Give the structures of `(A),(B)` and `(C)(`explanation is not required `).`
`i.` `(A)(C_(4)H_(8))` that adds on `HBr` in the presence and in the absence of peroxide to give the same product, `C_(4)H_(9)Br`.
`ii.` `(B)(C_(4)H_(8)),` which when treated with `H_(2)O //H_(2)SO_(4)` gives `C_(4)H_(10)O` that cannot be resolves into optical isomers.
`iii.` `(C)(C_(6)H_(12),` an optically active hydrocarbon which on catalytic hydrogenation gives an optically inactive compound, `C_(6)H_(14))`

Text Solution

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The correct Answer is:
`CH_(3)-CH_(2)-undersetunderset((CH_(6)H_(12)))(CH_(3))underset(|)overset(H)overset(|)(C)-CH=CH_(2)`
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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-5(B)
  1. Complete the following reactions: (i) CH(3)-overset(CH(3))overset(|)...

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  2. Identify the major product in the following reactions : C(6)H(5)-CH(...

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  3. Give the structures of (A),(B) and (C)(explanation is not required ). ...

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  4. Draw the stereochemical structures of the products in the following re...

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  5. Write down the structure of the stereoisomers formed when cis-2-butene...

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  6. An organic compound E (C5 H8) on hydrogenation gives compound F (C5 H(...

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  7. Give the structure of the major organic products obtained from 3-ethyl...

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  8. An alkyl halide (X)of the folmula C(6)H(13)Cl on treatment with potass...

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  9. A : When 3,3-dimethyl butan - 2 - ol is heated in presence of concentr...

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  10. Identify the compound (A), (B), and (C). Compound (A) (C(8)H(12))ove...

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  11. Compound (A) C(6)H(12) gives a positive test with bromine in carbon te...

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  12. Complete the following giving the structures of the principal organic ...

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  13. Give reasons for the following in one or two sentences ' The central c...

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  14. Write the intermediate steps for each of the following reactions

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  15. Write the intermediate steps for each of the following reactions (i)...

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  16. Complete the following -

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  17. Complete the following -

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  18. Carry out the following transformation in not more than three steps. ...

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  19. Give reasons for the following: CH2=CH^(Θ) is more basic than HC-=C^...

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  20. What would be the major product in the following reaction ?

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