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In which of the following reaction t-but...

In which of the following reaction `t-`butylbenzene is formed :

A

Benzene `+ t-`butyl chloride `overset(AlCl_(3))rarr`

B

Benzene `+(CH_(3))_(2)C=CH_(2)overset(BF_(3).HF)rarr`

C

Benzene + `t-butyl alcohol overset(H_(2)SO_(4))to`

D

All of these

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The correct Answer is:
To determine in which of the given reactions `t-butylbenzene` is formed, we can analyze each reaction step-by-step. ### Step-by-Step Solution: 1. **Identify the Reactions:** We need to analyze the three reactions provided in the question to see if they lead to the formation of `t-butylbenzene`. 2. **First Reaction: Friedel-Crafts Alkylation:** - In this reaction, `t-butyl chloride` is reacted with `benzene` in the presence of a `Lewis acid` (like AlCl3). - The `t-butyl chloride` can be represented as (CH3)3CCl. - The Lewis acid facilitates the formation of a `t-butyl cation` (a tertiary carbocation). - This cation then reacts with benzene, replacing one of the hydrogen atoms, resulting in the formation of `t-butylbenzene`. - **Conclusion:** This reaction produces `t-butylbenzene`. 3. **Second Reaction: Alkene Reaction with Benzene:** - Here, benzene is reacted with an alkene, specifically (CH3)2C=CH2 (which is isobutylene). - The double bond in the alkene breaks, and the carbon with the double bond attaches to the benzene ring. - This carbon is connected to three other carbons (making it a tertiary carbon), leading to the formation of `t-butylbenzene`. - **Conclusion:** This reaction also produces `t-butylbenzene`. 4. **Third Reaction: Reaction of Tertiary Butyl Alcohol:** - In this case, `t-butyl alcohol` (which can be represented as (CH3)3COH) is reacted in the presence of sulfuric acid (H2SO4). - The acid protonates the alcohol, leading to the formation of a `t-butyl cation`. - This cation then reacts with benzene, replacing one hydrogen atom and forming `t-butylbenzene`. - **Conclusion:** This reaction also produces `t-butylbenzene`. 5. **Final Conclusion:** Since all three reactions lead to the formation of `t-butylbenzene`, the answer to the question is that `t-butylbenzene` is formed in all of the reactions. ### Answer: All of these reactions produce `t-butylbenzene`. ---

To determine in which of the given reactions `t-butylbenzene` is formed, we can analyze each reaction step-by-step. ### Step-by-Step Solution: 1. **Identify the Reactions:** We need to analyze the three reactions provided in the question to see if they lead to the formation of `t-butylbenzene`. 2. **First Reaction: Friedel-Crafts Alkylation:** ...
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ALLEN-ALKENE, ALKANE & ALKYNE -EXCERSISE-3
  1. In which of the following reaction t-butylbenzene is formed :

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  2. True or False

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  3. Heating of beta-hydroxy acid gives lactones.

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  4. Hunsdiecker reaction involve free radical in intermediate steps.

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  5. Benzoic acid is stronger than methanoic acid but weaker than ethanoic ...

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  6. Acid halides are more reactive than acid amides towards the hydrolysis...

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  7. What happens when sodium benzoate is heated with soda lime?

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  8. pK(a) and K(a) of an acid are connected by the relation.......

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  9. Fill in the blank by choosing the appropriate word/words from those gi...

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  10. Hell-Volhard-Zelinsky reaction involves the replacement of an ...........

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  11. Carboxylic acids may be prepared by the reaction of Grigrand reagents ...

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  12. Statement-I: Unlike the gtC=O group of aldehydes and ketones, the C=O ...

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  13. Statement-I: CH(3)COCH(2)COOC(2)H(5) will give iodoform test. Becau...

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  14. Statement-1: Acetic acid does not undergo haloform test. and State...

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  15. Statement-I: Benzoic acid on nitration will give m- nitro benzoic ac...

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  16. Statement-I: Acyl halide are more reactive than acid substance amide t...

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  17. Amides undergo hydrolysis to yield carboxylic acid plus amine on heati...

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  18. Amides undergo hydrolysis to yield carboxylic acid plus amine on heati...

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  19. Acid halides are more reactive than acid amides towards the hydrolysis...

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  20. When is treated with two equivalent of methyl magnesium iodide a...

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  21. Ester gives nucleophilic addition reaction followed by elimination rea...

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