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Nitrobenzene reacts with Br(2) in the pr...

Nitrobenzene reacts with `Br_(2)` in the presence of `FeBr_(3)` to give `m-`bromonitrobenzene as the major product. Which of the following provides the reasons for the formation of `m-`bromonitrobenzene as the major product :

A

The electron density on meta carbon is more than on ortho and para position

B

The intermediate cabonium ion formed after initial attack of `Br^(+)` attack the meta position is least destabilzed.

C

Loss of aromaticity when `Br^(+)` attacks at the ortho and para positions and not at meta position

D

Easler loss of `H^(+)` to regain aromaticity form the meta position than from ortho and para positon.

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The correct Answer is:
A, B
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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-5
  1. The most basic compound among the following is-

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  2. Monochlorination of toluene in sunlight followed by hydrolysis with aq...

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  3. Nitrobenzene reacts with Br(2) in the presence of FeBr(3) to give m-br...

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  4. Examine the following two structures for the anilinium ion and choose ...

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  5. The major product of nitration of Benzoic acid is -

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  6. Most stable carbonium ion is :

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  7. Arrange in order of decresing trend towards S(E) reactions, {:("Chlo...

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  8. Among following statements on the nitration of aromatic compoun...

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  9. Nitrobenzene can be prepared from benzene by using a mixture of conc....

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  10. Benzyl chloride can be prepared from toluene by chlorination with

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  11. The most unlikely resonating structures of pnitrophenoxide ion is :

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  12. The reaction of with HBr gives :

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  13. A new C-C bond is formed in-

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  14. Benzenediazonium chloride on reaction with phenol in weakly basic medi...

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  15. Toluene, when treated with Br(2)Fe, gives o and p-bromotoluene, becaus...

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  16. Among the following, the strongest base is:

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  17. Identify the correct order of reactivity in electrophilic substitution...

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  18. (A) overset(NaNO(2)//HCl)underset((ii)H(2)//Ni)underset(0-5^(@))(rarr)...

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  19. Major product in this reaction is :

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  20. 4-Methyl benzene sulphoic acid reacts with sodium acetate to give :

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