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CH(3)CH(2)CH(2)OHoverset(PBr(5))rarr(A)o...

`CH_(3)CH_(2)CH_(2)OHoverset(PBr_(5))rarr(A)overset(KOH(Alc))rarr(B)overset(HBr)rarr(C)overset(NH_(3))rarr(D)`
Identify the product

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The correct Answer is:
To solve the question step by step, let's analyze the reactions one by one. ### Step 1: Reaction of Propanol with PBr5 The starting compound is propanol (CH₃CH₂CH₂OH). When propanol reacts with phosphorus pentabromide (PBr₅), it undergoes a substitution reaction where the hydroxyl group (-OH) is replaced by a bromine atom (Br). **Reaction:** \[ \text{CH}_3\text{CH}_2\text{CH}_2\text{OH} + \text{PBr}_5 \rightarrow \text{CH}_3\text{CH}_2\text{CH}_2\text{Br} + \text{POBr}_3 + \text{HBr} \] **Product A:** - The product formed is 1-bromopropane (CH₃CH₂CH₂Br). ### Step 2: Reaction of Product A with Alcoholic KOH Next, the product A (1-bromopropane) reacts with alcoholic KOH. This reaction leads to an elimination reaction (dehydrohalogenation), where HBr is eliminated, resulting in the formation of an alkene. **Reaction:** \[ \text{CH}_3\text{CH}_2\text{CH}_2\text{Br} + \text{KOH (alc)} \rightarrow \text{CH}_3\text{CH}=\text{CH}_2 + \text{HBr} \] **Product B:** - The product formed is propene (CH₃CH=CH₂). ### Step 3: Reaction of Product B with HBr Now, propene (Product B) reacts with HBr. According to Markovnikov's rule, the bromine will add to the more substituted carbon atom. **Reaction:** \[ \text{CH}_3\text{CH}=\text{CH}_2 + \text{HBr} \rightarrow \text{CH}_3\text{CHBrCH}_3 \] **Product C:** - The product formed is 2-bromopropane (CH₃CHBrCH₃). ### Step 4: Reaction of Product C with Ammonia Finally, 2-bromopropane (Product C) reacts with ammonia (NH₃). This reaction leads to the formation of an amine through nucleophilic substitution, where the bromine is replaced by an amino group (-NH₂). **Reaction:** \[ \text{CH}_3\text{CHBrCH}_3 + \text{NH}_3 \rightarrow \text{CH}_3\text{CH(NH}_2)\text{CH}_3 + \text{HBr} \] **Product D:** - The product formed is propan-2-amine (CH₃CH(NH₂)CH₃). ### Summary of Products: - **Product A:** 1-bromopropane (CH₃CH₂CH₂Br) - **Product B:** Propene (CH₃CH=CH₂) - **Product C:** 2-bromopropane (CH₃CHBrCH₃) - **Product D:** Propan-2-amine (CH₃CH(NH₂)CH₃) ### Final Answer: The final product D is propan-2-amine (CH₃CH(NH₂)CH₃). ---
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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-4[A]
  1. What are the major products of the following :

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  2. C(2)H(5)OHoverset(PCl(5))rarr(A)overset(KCN)rarr(B)overset(H(3)O^(+))r...

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  3. CH(3)CH(2)CH(2)OHoverset(PBr(5))rarr(A)overset(KOH(Alc))rarr(B)overset...

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  4. Why tertiary alcohols react less rapidly with metallic sodium than do...

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  5. Explain why ArOR ethers are cleaved to give RI and ArOH rather than ...

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  6. Complete the following reactions:

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  7. Complete the following reactions: (a) (b)

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  8. Provide products in the following reactions:

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  9. Identify the products A and B giving proper explanation : (a)

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  10. Indicate bonds which are cleaved I: In basic contions II: in acidic ...

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  12. Which of the carbonyl groups in p-MeOC(6)H(4)COMe and p-NO(2)C(6)H(4)C...

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  13. Identify (A) in the given sequence of reaction PhCH(2)CHOoverset(SeO...

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  16. (a) The double bond in aldehydes and ketones is reactive towards nucle...

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  17. Complete the following equations giving the structures of the major or...

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  18. Complete the following equation: (b)

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  19. Two organic compounds (A) and (B) have same empirical formula CH(2)O. ...

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  20. CH-=CHoverset(NaNH(2))to[A]overset(CH(3)Br)to[B]

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