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Hydration of 3-phenylbut-1-ene in dil H(...

Hydration of 3-phenylbut-1-ene in dil `H_(2)So_(4)` will give mainly :

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The correct Answer is:
`H_(2)C=CH-underset(Ph)underset(|)CH-CH_(3)overset(H^(+))rarrH_(3)C-overset(+)CH-underset(Ph)underset(|)CH-CH_(3)overset(-H)rarrH_(3)C-CH_(2)-underset(Ph)overset(+)C-CH_(3)`
`underset(-H^(+))overset(H_(2)O)rarrCH_(3)CH_(2)-underset(Ph)underset(|)overset(OH)overset(|)C-CH_(3)`
(Hydration gives an intermediate `2^(@)C`, which undergoes a hydride shift Although phenyl is a better migrator than `H`, migration of H oC Curs leading to a more stable `3^(@)` benzylic carbocation.)
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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-4[B]
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  2. Give the product of the reaction of Ph(2)CHCH(2)OH with HBr and explai...

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  3. Hydration of 3-phenylbut-1-ene in dil H(2)So(4) will give mainly :

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  4. When A given bel,ow reacts with HI products is B and not C. Explain

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  5. Isotopic carbon-14 in (A) appears at new position (As in B) (A) reacts...

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  6. Complete the following reaction

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  7. Complete the following reactions CH(3)CH=CH(2)overset(mCPBA)rarr A ...

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  8. In the following dehydration of diol with H(3)PO(4) following product ...

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  9. In the following S(N)1 reaction: underset(S(N)1)overset(OH^(o+))rar...

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  10. Identify (A) to (C) as reactant, reagent, product as name of the react...

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  11. Two different Grignard reagents (X) and (Y ) produce C(6)H(5)CH(2)C(CH...

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  12. (a) 2-methyl-1,3-cyclohexanedione is more acidic than cyclohexane - ex...

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  13. A substance C(5)H(10)O does not reduce Fehling's solution, forms a phe...

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  14. Convert PhCHO into PhCH=CHCOPh

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  15. A ketone [A] which undergoes haloform reactions gives compound [B] on ...

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  16. The sodium salt of a carboxylic acid (A) was produced by passing a gas...

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  17. Give reasons for the following: (a) Ketones are less electrophilic t...

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  18. Identify A, B and C ?

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  19. Identify A to E

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  20. CH(3)COO^(-) (acetate ion) is more stable than C(2)H(5)O^(-) (ethoxide...

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