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Reagent used to convert allyl alcohol to...

Reagent used to convert allyl alcohol to acrolein is :

A

`MnO_(2)`

B

`KMnO_(4)`

C

`O_(s)O_(4)`

D

`H_(2)O_(2)`

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AI Generated Solution

The correct Answer is:
To convert allyl alcohol to acrolein, we need to follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The starting compound is allyl alcohol, which has the structure CH2=CH-CH2OH. 2. **Identify the Product**: - The desired product is acrolein, which has the structure CH2=CH-CHO. 3. **Understand the Reaction Type**: - The conversion involves oxidation of the alcohol functional group (-OH) to an aldehyde (-CHO). 4. **Select the Appropriate Reagent**: - The reagent that can facilitate this oxidation without affecting the double bond is manganese dioxide (MnO2). 5. **Reaction Conditions**: - The reaction is typically carried out in the presence of an inert solvent such as dichloromethane (CH2Cl2) or carbon tetrachloride (CCl4) to maintain mild and neutral conditions. 6. **Mechanism of the Reaction**: - MnO2 selectively oxidizes the allylic alcohol to the corresponding aldehyde (acrolein) without attacking the double bond. 7. **Conclusion**: - Therefore, the reagent used to convert allyl alcohol to acrolein is manganese dioxide (MnO2). ### Final Answer: The reagent used to convert allyl alcohol to acrolein is **MnO2 (manganese dioxide)**. ---
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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-5[A]
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  2. Synthetic polymer bakelite can be prepared from following compounds:-

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