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In the reaction sequence RCOCl+H(2)ove...

In the reaction sequence
`RCOCl+H_(2)overset(Pd+BaSO_(4))rarrAoverset(HCN)rarrBoverset(H_(3)O^(o+))rarrC`
A,B and C are given by the set :-

A

`RCHO,RCH(OH)CN, RCH(OH)CH_(2)NH_(2)`

B

`RCHO, RCH(OH)CN, RCH(OH)COOH`

C

`RCHO,R-underset(O)underset(||)C-underset(CN)underset(|)CH_(2),R-underset(O)underset(||)C-OH`

D

`RCHO,R-CH_(2)-CN,R-CH_(2)-COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reaction sequence, we will analyze each step carefully. ### Step-by-Step Solution: 1. **Identify the Starting Material**: The starting material is RCOCl (an acyl chloride). 2. **First Reaction**: The first reaction involves RCOCl reacting with H2 in the presence of Pd/BaSO4. This is a Rosenmund reduction, which converts acyl chlorides to aldehydes. - **Product A**: The product of this reaction is RCHO (an aldehyde). 3. **Second Reaction**: The aldehyde (RCHO) then reacts with HCN (hydrogen cyanide). In this reaction, the carbonyl carbon of the aldehyde is attacked by the cyanide ion (CN⁻), leading to the formation of a cyanohydrin. - **Product B**: The product of this reaction is RCH(OH)CN (the cyanohydrin). 4. **Third Reaction**: The cyanohydrin (RCH(OH)CN) is then treated with H3O⁺ (acidic conditions). Under acidic conditions, the cyanohydrin undergoes hydrolysis, converting the cyano group (CN) into a carboxylic acid (COOH). - **Product C**: The final product is RCOOH (a carboxylic acid). ### Summary of Products: - **A**: RCHO (aldehyde) - **B**: RCH(OH)CN (cyanohydrin) - **C**: RCOOH (carboxylic acid) ### Final Answer: The correct set of products A, B, and C is: - A = RCHO - B = RCH(OH)CN - C = RCOOH
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