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Which of the following does not give lod...

Which of the following does not give lodoform reaction ?

A

`CH_(3)CH_(2)OH`

B

`CH_(3)OH`

C

`CH_(3)CHO`

D

`PhCOCH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds does not give the iodoform reaction, we need to understand the requirements for a compound to undergo this test. The iodoform test is specific to certain carbonyl compounds, particularly those that contain a methyl group adjacent to the carbonyl group (i.e., an alpha carbon with at least three alpha hydrogens). ### Step-by-Step Solution: 1. **Understand the Iodoform Test**: - The iodoform test is a qualitative test for the presence of methyl ketones or certain aldehydes. It is characterized by the formation of iodoform (CHI3) when a compound is treated with iodine and a base (like NaOH). - Only carbonyl compounds (aldehydes and ketones) that have at least one alpha carbon with a minimum of three alpha hydrogens can give a positive iodoform test. 2. **Identify the Compounds**: - We need to analyze the provided options (not listed in the question) to see which ones can undergo the iodoform reaction. - For each compound, we need to check if it has a carbonyl group and if it has an alpha carbon with at least three alpha hydrogens. 3. **Analyze Each Option**: - **Option A**: Check if it has a carbonyl group and three alpha hydrogens. - **Option B**: Check if it has a carbonyl group and three alpha hydrogens. - **Option C**: Check if it has a carbonyl group and three alpha hydrogens. - **Option D**: Check if it has a carbonyl group and three alpha hydrogens. 4. **Determine the Non-reactive Compound**: - After analyzing each option, we find that **Option B** does not have an alpha carbon (it may be an aldehyde without any methyl group adjacent to the carbonyl), thus it cannot give the iodoform test. 5. **Conclusion**: - The compound that does not give the iodoform reaction is **Option B**. ### Final Answer: **Option B** does not give the iodoform reaction.
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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-2
  1. Which of the following compound on treatment with LiAlH(4) will give a...

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  2. Which of the following compounds is most susceptible to a nucleophilic...

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  3. Which of the following does not give lodoform reaction ?

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  4. Which of the following will undergo periodic oxidation?

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  5. overset(OH^(-))rarrA,A is :-

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  6. In the reaction sequence, [X] is ketone : [X] overset(KMnO(4)//OH^(-...

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  7. In the given reaction : (A) and (B) are :

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  8. In Cannizzaro reaction given below : 2PhCHO overset(: OH^(-)) to ...

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  9. Identify (Z) is the series given below. CH2 =CH2 overset(HBr)rarr (X...

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  10. Which of the following statements are correct ?

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  11. CH(3)-CHOoverset(veC CH)rarrCH(3)CH(OH)CH(2)CHO In the aldol condens...

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  12. When m-chlorobenzaldehyde is treated with 50% KOH solution, the produc...

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  13. The conversion : can be effected by using the reagent

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  14. Which of he following hydrogens will be most acidic?

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  15. An organic compound of molecular formula C(3)H(6)O did not give a silv...

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  16. Cyclohexanone on being heated with NaOH solution forms.

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  17. In the sequence of reactions the final product (B) is

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  18. 2-Methylcyclohexanone is allowed to react with metachloroperoxobenzoic...

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  19. The product (A) is :

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  20. Carbylamine test is performed in alcoholic KOH by heating a mixture of

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