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In the reaction sequence, [X] is ketone ...

In the reaction sequence, [X] is ketone :
`[X] overset(KMnO_(4)//OH^(-)//Delta)rarrHOOC(CH_(2))_(3)-overset(CH_(3))overset(|)CH-COOH`
[X] will be :-

A

B

C

D

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AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the structure of the ketone [X] that, when treated with KMnO4 in the presence of OH- and heat (Δ), yields the product HOOC(CH2)3-CH(CH3)-COOH. ### Step-by-Step Solution: 1. **Identify the Product Structure**: The product given is HOOC(CH2)3-CH(CH3)-COOH. This indicates that the product is a dicarboxylic acid with a total of 7 carbon atoms. The structure can be broken down as follows: - Two carboxylic acid groups (HOOC). - A straight chain of 3 methylene groups (CH2) connecting the two carboxylic acid groups. - A methyl group (CH3) attached to the central carbon. 2. **Count the Carbons**: Counting the carbon atoms in the product: - 2 from the carboxylic acid groups (1 from each). - 3 from the (CH2)3 chain. - 1 from the central carbon (which has the methyl substituent). - Total = 2 + 3 + 1 = 6 carbon atoms from the chain, plus 1 from the methyl group = 7 carbon atoms. 3. **Determine the Ketone Structure**: Since the oxidation of a ketone leads to the cleavage of the carbon chain, we need to find a ketone that, when oxidized, will yield the above product. The ketone must have a structure that allows for the formation of two carboxylic acids upon oxidation. 4. **Consider Possible Ketones**: The ketone must have a total of 7 carbon atoms. The possible structures can be: - A ketone with a methyl group on one side and a longer carbon chain on the other. - The oxidation of this ketone should lead to the cleavage of the carbon chain at the ketone position. 5. **Choose the Correct Option**: From the options provided, we need to find a ketone that matches this description. - Option B suggests cyclohexanone with a methyl group. - When oxidized, this structure can lead to the formation of the desired product, as it has the correct number of carbon atoms and the necessary substituents. 6. **Conclusion**: Therefore, the correct ketone [X] that will yield the product upon oxidation with KMnO4 is **option B**. ### Final Answer: The ketone [X] is **option B**.
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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-2
  1. Which of the following will undergo periodic oxidation?

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  2. overset(OH^(-))rarrA,A is :-

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  3. In the reaction sequence, [X] is ketone : [X] overset(KMnO(4)//OH^(-...

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  4. In the given reaction : (A) and (B) are :

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  5. In Cannizzaro reaction given below : 2PhCHO overset(: OH^(-)) to ...

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  6. Identify (Z) is the series given below. CH2 =CH2 overset(HBr)rarr (X...

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  7. Which of the following statements are correct ?

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  8. CH(3)-CHOoverset(veC CH)rarrCH(3)CH(OH)CH(2)CHO In the aldol condens...

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  9. When m-chlorobenzaldehyde is treated with 50% KOH solution, the produc...

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  10. The conversion : can be effected by using the reagent

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  11. Which of he following hydrogens will be most acidic?

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  12. An organic compound of molecular formula C(3)H(6)O did not give a silv...

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  13. Cyclohexanone on being heated with NaOH solution forms.

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  14. In the sequence of reactions the final product (B) is

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  15. 2-Methylcyclohexanone is allowed to react with metachloroperoxobenzoic...

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  16. The product (A) is :

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  17. Carbylamine test is performed in alcoholic KOH by heating a mixture of

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  18. Acetamide is treated with the following reagents separately. Which one...

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  19. Maximum basic in gas phase is ?

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  20. Benzenediazonium chloride on reaction with aniline in weakly basic med...

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