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CH(3)-CHOoverset(veC CH)rarrCH(3)CH(OH)C...

`CH_(3)-CHOoverset(veC CH)rarrCH_(3)CH(OH)CH_(2)CHO`
In the aldol condensation of acetaldehyde represented above, which of the following intermediate species as obtained?

A

B

C

D

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The correct Answer is:
To solve the problem regarding the aldol condensation of acetaldehyde (CH₃CHO), we will break down the reaction step-by-step and identify the intermediate species formed during the process. ### Step-by-Step Solution: 1. **Identify the Reactant**: The reactant in this case is acetaldehyde, which has the structure CH₃CHO. 2. **Formation of Enolate Ion**: In the presence of a dilute base (like OH⁻), the acidic hydrogen from the alpha carbon (the carbon adjacent to the carbonyl group) is abstracted. This results in the formation of an enolate ion. - The enolate ion can be represented as CH₂=CHO⁻ (with the negative charge on the oxygen). 3. **Nucleophilic Attack**: The enolate ion acts as a nucleophile and attacks the carbonyl carbon of another acetaldehyde molecule. This results in the formation of a β-hydroxy aldehyde intermediate. - The structure of this intermediate can be represented as CH₃CH(OH)CH₂CHO. 4. **Dehydration**: The β-hydroxy aldehyde can undergo dehydration (loss of water) to form an α,β-unsaturated aldehyde. However, the question specifically asks for the intermediate species obtained, which is the β-hydroxy aldehyde. - The final product after dehydration would be CH₃CH=CHCHO, but we focus on the intermediate. 5. **Conclusion**: The intermediate species formed during the aldol condensation of acetaldehyde is the β-hydroxy aldehyde, CH₃CH(OH)CH₂CHO. ### Answer: The intermediate species obtained in the aldol condensation of acetaldehyde is CH₃CH(OH)CH₂CHO.
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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-2
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  2. Which of the following statements are correct ?

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  3. CH(3)-CHOoverset(veC CH)rarrCH(3)CH(OH)CH(2)CHO In the aldol condens...

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  4. When m-chlorobenzaldehyde is treated with 50% KOH solution, the produc...

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  5. The conversion : can be effected by using the reagent

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  6. Which of he following hydrogens will be most acidic?

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  7. An organic compound of molecular formula C(3)H(6)O did not give a silv...

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  8. Cyclohexanone on being heated with NaOH solution forms.

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  9. In the sequence of reactions the final product (B) is

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  10. 2-Methylcyclohexanone is allowed to react with metachloroperoxobenzoic...

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  11. The product (A) is :

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  12. Carbylamine test is performed in alcoholic KOH by heating a mixture of

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  13. Acetamide is treated with the following reagents separately. Which one...

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  14. Maximum basic in gas phase is ?

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  15. Benzenediazonium chloride on reaction with aniline in weakly basic med...

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  16. Which of the following statements is correct ?

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  17. Which of the following statements is correct?

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  18. Which of the following statements is correct ?

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  19. The correct order of base strength of substituted aniline is

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  20. Consider the following reaction , C(6)H(5)NH(2)+CHCl(3)+KOHoverset(D...

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