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In the following sequence of reactions: ...

In the following sequence of reactions:
`CH_(3)CH_(2)CH_(2)OHoverset(P+I_(2))rarrAoverset(Mg)underset("dry ether")rarrBoverset(HCHO)rarrCoverset(H_(2)O)rarrD` the compound `D` is:

A

butanal

B

n-butyl alcohol

C

n-propyl alcohol

D

propanal

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The correct Answer is:
To solve the problem step by step, we will analyze each reaction in the sequence provided: ### Step 1: Identify the starting compound The starting compound is **CH₃CH₂CH₂OH**, which is **1-butanol**. ### Step 2: Reaction with phosphorus and iodine When 1-butanol reacts with phosphorus (P) and iodine (I₂), it undergoes a halogenation reaction to form **1-bromobutane** (or **1-iodobutane**). The reaction can be summarized as: \[ \text{CH}_3\text{CH}_2\text{CH}_2\text{OH} + \text{P} + \text{I}_2 \rightarrow \text{CH}_3\text{CH}_2\text{CH}_2\text{I} \] This compound is now referred to as **A**. ### Step 3: Formation of Grignard reagent Next, the compound A (1-iodobutane) reacts with magnesium (Mg) in dry ether to form the Grignard reagent: \[ \text{CH}_3\text{CH}_2\text{CH}_2\text{I} + \text{Mg} \rightarrow \text{CH}_3\text{CH}_2\text{CH}_2\text{MgI} \] This compound is now referred to as **B**. ### Step 4: Reaction with formaldehyde The Grignard reagent (B) then reacts with formaldehyde (HCHO). The reaction is as follows: \[ \text{CH}_3\text{CH}_2\text{CH}_2\text{MgI} + \text{HCHO} \rightarrow \text{CH}_3\text{CH}_2\text{CH}_2\text{CH}_2\text{OH} \] This results in the formation of a new alcohol, which is now referred to as **C**. ### Step 5: Hydrolysis of the Grignard addition product Finally, the addition product (C) is hydrolyzed with water (H₂O): \[ \text{CH}_3\text{CH}_2\text{CH}_2\text{CH}_2\text{MgI} + \text{H}_2\text{O} \rightarrow \text{CH}_3\text{CH}_2\text{CH}_2\text{CH}_2\text{OH} + \text{Mg(OH)I} \] This gives us **n-butanol** (or **1-butanol**), which is now referred to as **D**. ### Conclusion The final compound D is **n-butanol** (or **1-butanol**). ### Summary of Steps: 1. Start with 1-butanol (CH₃CH₂CH₂OH). 2. React with P and I₂ to form 1-iodobutane (A). 3. React A with Mg in dry ether to form the Grignard reagent (B). 4. React B with formaldehyde (HCHO) to form the addition product (C). 5. Hydrolyze C with water to form n-butanol (D).
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