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An organic compound (A) on treatment wit...

An organic compound `(A)` on treatment with ethyl alcohol gives a carboxylic acid `(B)` and compound `( C)`. The hydrolysis of `( C)` under acidic conditions gives `(B)` and `(D)`. Oxidation of `(D)` with `KMnO_4` also gives `(B)`. `(B)` on heating with `Ca(OH)_2` gives `(E)` (molecular formula, `C_3 H_6 O`). `(E)` does not give Tollens test and does not reduce Fehling's solution but forms a `2,4-`dinitrophenyl hydrazone. Identify `(A),(B), ( C), (D)`, and `(E)`.

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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-5[B]
  1. (a) Give chemical tests to distinguish between compounds in the follo...

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  2. Give reasons: iodoform is obtained by the reaction of acetone with h...

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  3. An organic compound (A) on treatment with ethyl alcohol gives a carbox...

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  4. Complete the following : A and B is

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  5. Complete the following reaction with appropriate structure. C(6)H(5)...

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  6. Complete the following reaction with appropriate structure:

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  7. overset("Cold dil.alk ,KMnO"(4))rarrXoverset(HlO(4))rarr overset(OH^(-...

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  8. Complete the following :

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  9. Compound (A) (C(8)H(8)O) on treatment with NH(2)OH.HCl gives (B) and (...

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  10. Carry out the following transformation in not more than three steps. ...

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  11. An organic compound (A) (C(6)H(10)O) on reaction with CH(3)MgBr follow...

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  12. An organic compound (A) reacts with H(2) to give (B) and (C) successiv...

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  13. What'is X?

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  14. 1^("st") member of ketone family and its next homologue reacts with NH...

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  15. Cyclohexene on ozonolysis followed by reaction with zinc dust and wate...

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  16. Statemet-1 : Glucose gives a reddish-brown precipitate with Fehling's ...

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  17. In the following reaction sequence, products I, J, and L are formed. K...

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  18. In the following reaction sequence, products I, J, and L are formed. K...

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  19. In the following reaction sequence, products I, J, and L are formed. K...

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  20. A tertiary alcohol (H) upon acid-catalysed dehydration gives a product...

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