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On subjecting mesityl oxide to the iodof...

On subjecting mesityl oxide to the iodoform reaction, one of the products is the sodium salt of an orgnic acid. Which acid is obtained?

A

`(CH_(3))_(2)C=CH-CH_(2)COOH`

B

`(CH_(3))_(2)CH-COOH`

C

`(CH_(3))_(2)C=CH-COOH`

D

`(CH_(3))_(2)C=CH-CO-COOH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the iodoform reaction of mesityl oxide and identify the organic acid produced, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of Mesityl Oxide**: - Mesityl oxide is a ketone with the formula \( \text{C}_6\text{H}_{10}\text{O} \) and can be represented as \( \text{CH}_3\text{C}(=O)\text{C}(\text{CH}_3)=\text{CH}_2\text{CH}_3 \). 2. **Understand the Iodoform Reaction**: - The iodoform reaction occurs with methyl ketones or compounds that can be converted into methyl ketones. In this reaction, the compound reacts with iodine (\( \text{I}_2 \)) in the presence of a base (usually sodium hydroxide, \( \text{NaOH} \)) to produce iodoform (\( \text{CHI}_3 \)) and a sodium salt of an organic acid. 3. **Reaction of Mesityl Oxide**: - When mesityl oxide is subjected to the iodoform reaction, it will undergo halogenation and oxidation. The reaction can be summarized as: \[ \text{CH}_3\text{C}(=O)\text{C}(\text{CH}_3)=\text{CH}_2 + \text{I}_2 + \text{NaOH} \rightarrow \text{CHI}_3 + \text{CH}_3\text{C}(=O)\text{O}^- \text{Na}^+ \] 4. **Identify the Organic Acid**: - The sodium salt formed in the reaction is the sodium salt of acetic acid (\( \text{CH}_3\text{COO}^- \text{Na}^+ \)). This is because the iodoform reaction typically leads to the formation of acetic acid when a methyl ketone is involved. 5. **Conclusion**: - Therefore, the organic acid obtained from the iodoform reaction of mesityl oxide is **sodium acetate** (the sodium salt of acetic acid). ### Final Answer: The acid obtained is **sodium acetate**.

To solve the question regarding the iodoform reaction of mesityl oxide and identify the organic acid produced, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of Mesityl Oxide**: - Mesityl oxide is a ketone with the formula \( \text{C}_6\text{H}_{10}\text{O} \) and can be represented as \( \text{CH}_3\text{C}(=O)\text{C}(\text{CH}_3)=\text{CH}_2\text{CH}_3 \). 2. **Understand the Iodoform Reaction**: ...
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Knowledge Check

  • Which alkane is produced when sodium salt of butanoic acid is heated with soda lime?

    A
    `CH_(3)CH_(3)`
    B
    `CH_(3)CH_(2)CH_(2)CH_(3)`
    C
    `CH_(4)`
    D
    `CH_(3)CH_(2)CH_(3)`
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