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HVZ reaction is specific for -...

HVZ reaction is specific for -

A

Replacement of `beta-`hydrogens

B

Replacement of `alpha-`hydrogens

C

Replaceent of `beta-`carbons

D

Replacement of `alpha-`carbons

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**Step-by-Step Solution:** 1. **Understanding the HVZ Reaction**: The Hell-Wolhard-Zelinsky (HVZ) reaction is a chemical reaction that involves the halogenation of carboxylic acids. It specifically targets the alpha-hydrogen of the carboxylic acid. 2. **Reactants Involved**: In the HVZ reaction, we start with a carboxylic acid (RCH2COOH) and halogens (like Cl2 or Br2) in the presence of red phosphorus. 3. **Mechanism of the Reaction**: - The reaction proceeds by the halogenation of the alpha position (the carbon adjacent to the carboxylic acid group). - The red phosphorus acts as a reducing agent, facilitating the halogenation process. 4. **Formation of Alpha Halo Carboxylic Acids**: The result of the HVZ reaction is the formation of alpha halo carboxylic acids (RCHXCOOH), where X is the halogen (Cl or Br). The alpha-hydrogen is replaced by a halogen atom. 5. **Example**: For example, if we take butanoic acid (CH3CH2COOH): - First, with Br2 and red phosphorus, the alpha-hydrogen is replaced, resulting in CH3CHBrCOOH (2-bromobutanoic acid). - If the reaction is repeated, we can replace another alpha-hydrogen, yielding CH3CBr2COOH (2,2-dibromobutanoic acid). 6. **Conclusion**: The HVZ reaction is specific for carboxylic acids, particularly focusing on the halogenation of the alpha-hydrogen to form alpha halo carboxylic acids. **Final Answer**: The HVZ reaction is specific for carboxylic acids. ---
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ALLEN-ALKENE, ALKANE & ALKYNE -EXCERSISE-1
  1. A: Reaction of carboxylic acid with hydrazoic acid in the presence of ...

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  2. Ethyl ester overset(CH(3)MgBr)underset("excess")rarrP, the product P i...

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  3. HVZ reaction is specific for -

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  4. (a) Give chemical tests to distinguish between the following pairs of ...

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  5. Benzoic acid reacts with Ca(OH)(2). The product obtained on dry distil...

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  6. In a set of the given reactions, acetic acid yielded a product iC. CH...

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  7. The correct reactivity order with the nucleophile is :

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  8. CH(3)-CH(2)-underset(O)underset(||)C-NH(2)overset(A)rarrCH(3)-CH(2)-NH...

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  9. Ethyl acetate on treatmemt with Hydrazine gives-

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  10. Which amongst the following is the strongest acid ?

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  11. In the Rosenmund's reduction , BaSO(4) taken with catalyst Pd acts as ...

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  12. Which of the following carboxylic acid undergoes decarboxylation easil...

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  13. The order of reactivity of various alkyl halides towards nucleophilic ...

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  14. In the following sequence of reaction the product B is :

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  15. Consider the following reaction.

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  16. Which of the following orders regarding the base strength of a leaving...

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  17. The correct decreasing order of their reactivity towards hydrolysis is

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  18. Kolbe's electrolysis of potassium succinate gives CO(2) and ……………………

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  19. In the following reactions. Identify the compounds A, B, C and D PCl(...

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  20. Complete the following reaction: CH(3)CH(2)COOHoverset(P,Br(2))to[A]...

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