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CH(3)-CH(2)-underset(O)underset(||)C-NH(...

`CH_(3)-CH_(2)-underset(O)underset(||)C-NH_(2)overset(A)rarrCH_(3)-CH_(2)-NH_(2)`
`overset(B)rarrCH_(3)-CH_(2)-OH`
In the above sequence A `&` B respectively are-

A

`Br_(2)//KOH,NaOH`

B

`Br_(2)//KOH,HNO_(2)`

C

`KMnO_(4),KOH`

D

`HNO_(2),Br_(2)//KOH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to identify the reactions represented by A and B in the conversion sequence: 1. **Starting Compound**: CH₃-CH₂-C(=O)-NH₂ (This is a primary amide). 2. **Final Products**: CH₃-CH₂-NH₂ (This is a primary amine) and CH₃-CH₂-OH (This is a primary alcohol). ### Step 1: Identify Reaction A The conversion from a primary amide to a primary amine can be achieved through the Hofmann degradation reaction. In this reaction, the amide is treated with bromine (Br₂) in the presence of a strong base like potassium hydroxide (KOH). **Reaction A**: - **Reagents**: Br₂ and KOH - **Process**: The amide reacts to form a primary amine by losing one carbon atom. The reaction involves the formation of an intermediate that rearranges and undergoes hydrolysis to yield the amine. ### Step 2: Identify Reaction B The conversion from a primary amine to a primary alcohol can be achieved by treating the amine with nitrous acid (HNO₂). This reaction leads to the formation of an alcohol along with nitrogen gas and water. **Reaction B**: - **Reagents**: HNO₂ (Nitrous acid) - **Process**: The primary amine reacts with nitrous acid to form the corresponding alcohol, nitrogen gas, and water. ### Final Answer Thus, the reactions A and B respectively are: - **A**: Br₂ + KOH (Hofmann degradation) - **B**: HNO₂ (Nitrous acid reaction) ### Summary of Steps 1. Identify the starting compound as a primary amide. 2. Recognize that the conversion to a primary amine involves Hofmann degradation (Br₂ + KOH). 3. Identify that the conversion from a primary amine to a primary alcohol involves treatment with nitrous acid (HNO₂).
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ALLEN-ALKENE, ALKANE & ALKYNE -EXCERSISE-1
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  14. Consider the following reaction.

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  15. Which of the following orders regarding the base strength of a leaving...

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