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Carboxylic acids may be prepared by the ...

Carboxylic acids may be prepared by the reaction of Grigrand reagents with .........

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To prepare carboxylic acids using Grignard reagents, follow these steps: ### Step-by-Step Solution: 1. **Identify the Grignard Reagent**: - A Grignard reagent is generally represented as R-MgX, where R is an organic group (alkyl or aryl) and X is a halogen (like Cl, Br, or I). 2. **React with Carbon Dioxide**: - The Grignard reagent reacts with carbon dioxide (CO2). Carbon dioxide is a linear molecule with the structure O=C=O. 3. **Formation of the Addition Product**: - When the Grignard reagent (R-MgX) reacts with CO2, it forms an addition product. The carbon atom of CO2 acts as an electrophile and reacts with the nucleophilic carbon in the Grignard reagent. The product formed is R-C(=O)-MgX. 4. **Hydrolysis**: - The addition product (R-C(=O)-MgX) is then hydrolyzed by adding water (H2O) in the presence of an acid (H+). This step converts the addition product into a carboxylic acid (R-COOH) and produces magnesium hydroxide halide (Mg(OH)X). 5. **Final Product**: - The final product of this reaction is a carboxylic acid (R-COOH). ### Conclusion: Thus, carboxylic acids may be prepared by the reaction of Grignard reagents with carbon dioxide (CO2). ---
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ALLEN-ALKENE, ALKANE & ALKYNE -EXCERSISE-3
  1. Fill in the blank by choosing the appropriate word/words from those gi...

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  2. Hell-Volhard-Zelinsky reaction involves the replacement of an ...........

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  3. Carboxylic acids may be prepared by the reaction of Grigrand reagents ...

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  4. Statement-I: Unlike the gtC=O group of aldehydes and ketones, the C=O ...

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  5. Statement-I: CH(3)COCH(2)COOC(2)H(5) will give iodoform test. Becau...

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  6. Statement-1: Acetic acid does not undergo haloform test. and State...

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  7. Statement-I: Benzoic acid on nitration will give m- nitro benzoic ac...

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  8. Statement-I: Acyl halide are more reactive than acid substance amide t...

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  9. Amides undergo hydrolysis to yield carboxylic acid plus amine on heati...

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  10. Amides undergo hydrolysis to yield carboxylic acid plus amine on heati...

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  11. Acid halides are more reactive than acid amides towards the hydrolysis...

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  12. When is treated with two equivalent of methyl magnesium iodide a...

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  13. Ester gives nucleophilic addition reaction followed by elimination rea...

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  14. Ester gives nucleophilic addition reaction followed by elimination rea...

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  15. In the given reaction : C(2)H(5)O-overset(O)overset(||)C-(CH(2))(3)-CH...

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  16. In the given reaction [X] is :

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  17. The reactivity of acid derivatives in general follows the order : ...

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  18. The reactivity of acid derivatives in general follows the order : ...

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  19. The reactivity of acid derivatives in general follows the order : ...

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  20. The reactivity of acid derivatives in general follows the order : ...

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