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Statement-I: CH(3)COCH(2)COOC(2)H(5) wi...

Statement-I: `CH_(3)COCH_(2)COOC_(2)H_(5)` will give iodoform test.
Because
Statement-II: It contains `CH_(3)overset(O)overset(||)C-` group linked to a carbon atom.

A

Statement-I is True, Statement-II is True : Statement-II is a correct explanation for Statement-I

B

Statement-I is True, Statement-II is True : Statement-II is `NOT` a correct explanation for Statement-I

C

Statement-I is True, Statement-II is False.

D

Statement-I is False, Statement-II is True.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we need to analyze both statements regarding the compound \( CH_3COCH_2COOC_2H_5 \) and its ability to give the iodoform test. ### Step-by-Step Solution: 1. **Identify the Structure of the Compound**: The compound \( CH_3COCH_2COOC_2H_5 \) can be broken down as follows: - It contains a carbonyl group (C=O) from the \( CH_3CO \) part, which is an acetyl group. - The \( COOC_2H_5 \) part indicates that it is an ester (specifically, ethyl acetate). 2. **Understand the Iodoform Test**: The iodoform test is a qualitative test for the presence of methyl ketones (compounds with the structure \( RCOCH_3 \)) or compounds that can be oxidized to methyl ketones, such as secondary alcohols that can be converted to a methyl ketone. 3. **Analyze Statement-I**: Statement-I claims that \( CH_3COCH_2COOC_2H_5 \) will give the iodoform test. - Although the compound contains a \( CH_3CO \) group, it is part of an ester and not a methyl ketone. Esters do not give the iodoform test because they do not have the necessary structure (i.e., they do not have a terminal methyl group attached to the carbonyl carbon). 4. **Analyze Statement-II**: Statement-II states that it contains a \( CH_3CO \) group linked to a carbon atom. - This statement is true; the compound does indeed contain the \( CH_3CO \) group. 5. **Conclusion**: - Since Statement-I is false (the compound does not give the iodoform test) and Statement-II is true (the compound contains the \( CH_3CO \) group), we conclude that: - Statement-I: False - Statement-II: True ### Final Answer: - Statement-I is false, and Statement-II is true.
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ALLEN-ALKENE, ALKANE & ALKYNE -EXCERSISE-3
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  2. Carboxylic acids may be prepared by the reaction of Grigrand reagents ...

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  3. Statement-I: Unlike the gtC=O group of aldehydes and ketones, the C=O ...

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  4. Statement-I: CH(3)COCH(2)COOC(2)H(5) will give iodoform test. Becau...

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  5. Statement-1: Acetic acid does not undergo haloform test. and State...

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  6. Statement-I: Benzoic acid on nitration will give m- nitro benzoic ac...

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  7. Statement-I: Acyl halide are more reactive than acid substance amide t...

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  8. Amides undergo hydrolysis to yield carboxylic acid plus amine on heati...

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  9. Amides undergo hydrolysis to yield carboxylic acid plus amine on heati...

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  10. Acid halides are more reactive than acid amides towards the hydrolysis...

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  11. When is treated with two equivalent of methyl magnesium iodide a...

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  12. Ester gives nucleophilic addition reaction followed by elimination rea...

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  13. Ester gives nucleophilic addition reaction followed by elimination rea...

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  14. In the given reaction : C(2)H(5)O-overset(O)overset(||)C-(CH(2))(3)-CH...

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  16. The reactivity of acid derivatives in general follows the order : ...

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  17. The reactivity of acid derivatives in general follows the order : ...

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  18. The reactivity of acid derivatives in general follows the order : ...

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  20. The reactivity of acid derivatives in general follows the order : ...

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