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In the given reaction : C(2)H(5)O-overse...

In the given reaction : `C_(2)H_(5)O-overset(O)overset(||)C-(CH_(2))_(3)-CH_(2)-COOC_(2)H_(5)underset((ii)H_(2)O //HCl)overset((i)C_(2)H_(5)ONa//C_(2)H_(5)OH)rarr[X]`
[X] is :

A

B

C

D

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The correct Answer is:
To solve the given reaction and identify the product [X], we will follow these steps: ### Step 1: Identify the Reactants The reactants in the given reaction are: - Diethyl adipate (C2H5O-CO-(CH2)3-COOC2H5) - Sodium ethoxide (C2H5O-Na) - Ethanol (C2H5OH) - Hydrochloric acid (HCl) - Water (H2O) ### Step 2: Understand the Reaction Mechanism The reaction involves a condensation reaction known as the **Dieckmann condensation**, which occurs between two ester groups in the diethyl adipate. This reaction leads to the formation of a cyclic beta-ketoester. ### Step 3: Perform the Dieckmann Condensation 1. The sodium ethoxide acts as a base and deprotonates the ethanol, generating an alkoxide ion. 2. This alkoxide ion attacks one of the carbonyl carbons in the diethyl adipate, leading to the formation of a cyclic intermediate. 3. The cyclic intermediate then undergoes intramolecular condensation, resulting in the formation of a beta-ketoester. ### Step 4: Hydrolysis of the Beta-Ketoester 1. The beta-ketoester formed in the previous step is then subjected to hydrolysis in the presence of HCl and water. 2. This hydrolysis converts the beta-ketoester into a beta-keto acid. ### Step 5: Identify the Product [X] After hydrolysis, the final product [X] is a beta-keto acid. The structure of the beta-keto acid matches with the option provided in the question. ### Final Answer Thus, the product [X] is the beta-keto acid formed from the hydrolysis of the beta-ketoester. ---
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ALLEN-ALKENE, ALKANE & ALKYNE -EXCERSISE-3
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  2. Carboxylic acids may be prepared by the reaction of Grigrand reagents ...

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  3. Statement-I: Unlike the gtC=O group of aldehydes and ketones, the C=O ...

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  4. Statement-I: CH(3)COCH(2)COOC(2)H(5) will give iodoform test. Becau...

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  5. Statement-1: Acetic acid does not undergo haloform test. and State...

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  6. Statement-I: Benzoic acid on nitration will give m- nitro benzoic ac...

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  7. Statement-I: Acyl halide are more reactive than acid substance amide t...

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  8. Amides undergo hydrolysis to yield carboxylic acid plus amine on heati...

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  9. Amides undergo hydrolysis to yield carboxylic acid plus amine on heati...

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  10. Acid halides are more reactive than acid amides towards the hydrolysis...

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  11. When is treated with two equivalent of methyl magnesium iodide a...

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  12. Ester gives nucleophilic addition reaction followed by elimination rea...

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  13. Ester gives nucleophilic addition reaction followed by elimination rea...

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  14. In the given reaction : C(2)H(5)O-overset(O)overset(||)C-(CH(2))(3)-CH...

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  15. In the given reaction [X] is :

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  16. The reactivity of acid derivatives in general follows the order : ...

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  17. The reactivity of acid derivatives in general follows the order : ...

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  18. The reactivity of acid derivatives in general follows the order : ...

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  19. The reactivity of acid derivatives in general follows the order : ...

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  20. The reactivity of acid derivatives in general follows the order : ...

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