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In the reaction CH(3)COOH overset(LiAI...

In the reaction
`CH_(3)COOH overset(LiAIH_(4))rarr A overset(PCl_(g))rarrBoverset(Alc.KOH)rarrC`.
the product C is :

A

Ethylene

B

Acetyl chloride

C

Acetaldehyde

D

Acetylene

Text Solution

Verified by Experts

The correct Answer is:
A

`CH_(3)-overset(O)overset(||)C-OHoverset(LiAIH_(4))rarrCH_(3)overset((A))-CH_(2)-OHoverset(PCl_(5))rarr`
`CH_(3)overset((B))CH_(2)Cloverset(alc KOH)rarrCH_(2)overset((C))=CH_(2)`
Reduction of `CH_(3)COOH` will produce `CH_(3)-CH_(2)-OH(A)`
Now reaction of `CH_(3)-CH_(2)-OH(A)` with `PCl_(5)` will produce `CH_(3)-CH_(2)-Cl(B)`.
Now alcoholic KOH with `Et-Cl` will produce `CH_(2)=CH_(2)(C)` Ethylenen By `E_(2)` elemination Thus Ans. is (1) Ethylene.
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