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Two mole of an ester (A) are condensed i...

Two mole of an ester (A) are condensed in presence of sodium ethoxide to give a `beta-`keto ester (B) and ethanol. On heating in an acidic solution (B) gives ethanol and `beta-`keto acid (C). On decarboxylation (C) give 3-pentanone.
Identify (A),(B) and (C).

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To solve the problem step by step, let's identify the compounds A, B, and C based on the provided information. ### Step 1: Identify Compound A The question states that two moles of an ester (A) are condensed in the presence of sodium ethoxide. The general structure of an ester can be represented as RCOOR', where R and R' are alkyl groups. Given that the byproduct is ethanol (C2H5OH), we can deduce that one of the alkyl groups (R') in the ester must be ethyl (C2H5). Assuming R is a methyl group (CH3), the structure of ester A can be represented as: - **A: Ethyl acetate (CH3COOCH2CH3)** ### Step 2: Condensation Reaction to Form Compound B The condensation of two moles of ester A in the presence of sodium ethoxide leads to the formation of a beta-keto ester (B) and ethanol. This is a type of aldol condensation. The reaction can be summarized as follows: 1. The sodium ethoxide abstracts an alpha hydrogen from one ester molecule, forming a nucleophile. 2. This nucleophile then attacks the carbonyl carbon of another ester molecule, leading to the formation of a beta-keto ester. The structure of beta-keto ester B can be represented as: - **B: 3-oxobutanoate (CH3C(=O)C(=O)OCH2CH3)** ### Step 3: Heating Compound B to Form Compound C When compound B is heated in an acidic solution, it yields ethanol and a beta-keto acid (C). The reaction involves the hydrolysis of the beta-keto ester, resulting in the formation of a beta-keto acid. The structure of beta-keto acid C can be represented as: - **C: 3-oxobutanoic acid (CH3C(=O)C(=O)OH)** ### Step 4: Decarboxylation of Compound C The final step involves the decarboxylation of compound C, which results in the formation of 3-pentanone. Decarboxylation involves the removal of a carbon dioxide molecule (CO2) from the beta-keto acid. The structure of 3-pentanone can be represented as: - **3-pentanone: CH3C(=O)CH2CH2CH3** ### Summary of Compounds - **A:** Ethyl acetate (CH3COOCH2CH3) - **B:** 3-oxobutanoate (CH3C(=O)C(=O)OCH2CH3) - **C:** 3-oxobutanoic acid (CH3C(=O)C(=O)OH)
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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-5[B]
  1. Compound (A) (C(6)H(12)O(2)) on reduction with LiAlH(4) yielded two co...

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  2. The sodium salt of a carboxylic acid, A, was produced by passing a gas...

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  3. Two mole of an ester (A) are condensed in presence of sodium ethoxide ...

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  4. An organic compound (A) on treatment with ethyl alcohol gives a carbox...

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  5. An acidic compound (A) (C4 H8 O3) loses its optical activity on strong...

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  6. A liquid (X) having a molecular formula C(6) H(12) O(2) is hydrolysed ...

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  7. Acetophenone on reaction with hydroxyl amine hydrochloride can produce...

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  8. An organic acid (A), C(5)H(10)O(2) reacts with Br(2) in the presence o...

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  9. The IUPAC name of C(6) H(5) COC1 is :

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  10. Which of the following reactants on reaction with conc. NaOH followed ...

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  11. Identify the binary mixtrues (s) that can be separated nto the individ...

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  12. The total number of carboxylic acid groups in the product P is

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  13. The correct order of acidity for the following compounds is

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  14. Among the following compounds, which will react with acetone to give a...

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  15. The compound that will react most readily with NaOH to form methanol i...

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  16. Examine the following two structures for the anilinium ion and choose ...

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  17. Alkyl Isocyanide contains rho and pi bonds , as :

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  18. Nitrobenzene can be prepared from benzene by using a mixture of conc....

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  19. Among following statements on the nitration of aromatic compoun...

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  20. p-Chloroaniline and anilinium hydrochloride can be distinguished by :

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