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Which one of the following tests can be ...

Which one of the following tests can be used to identify primary
amino group in a given organic compound

A

lodoform test

B

Victor Meyer's test

C

Carbylamine reaction

D

Libermann's reaction

Text Solution

AI Generated Solution

The correct Answer is:
To identify a primary amino group in a given organic compound, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Question**: The question asks for a test that can specifically identify a primary amino group (NH2) in an organic compound. 2. **Reviewing the Tests**: We have four tests to consider: - Iodoform Test - Victor-Meyer Test - Carbolamine Reaction - Lieberman Reaction 3. **Analyzing the Iodoform Test**: - The Iodoform test is used to identify compounds that have a methyl ketone (CH3CO) or a secondary alcohol (CH3CHOH). - Since primary amines do not contain these functional groups, this test cannot be used to identify primary amino groups. **Hint**: Iodoform test is not suitable for primary amines as it targets specific carbonyl and alcohol structures. 4. **Analyzing the Victor-Meyer Test**: - The Victor-Meyer test is primarily used to distinguish between different types of alcohols (primary, secondary, and tertiary). - It does not apply to amines, hence it cannot identify primary amino groups. **Hint**: Victor-Meyer test is focused on alcohols, not amines. 5. **Analyzing the Carbolamine Reaction**: - The Carbolamine reaction involves the reaction of primary amines with chloroform (CHCl3) and alcoholic potassium hydroxide (KOH). - This reaction produces an isocyanide (R-N=C), which is a characteristic reaction for primary amines. Thus, this test can specifically identify primary amino groups. **Hint**: Carbolamine reaction is unique to primary amines and produces a distinct product. 6. **Analyzing the Lieberman Reaction**: - The Lieberman reaction is used to test for secondary amines. It does not apply to primary amines, making it an unsuitable choice for this question. **Hint**: Lieberman reaction is specific for secondary amines, not primary. 7. **Conclusion**: Based on the analysis, the test that can be used to identify a primary amino group is the **Carbolamine Reaction**. ### Final Answer: The test that can be used to identify a primary amino group in a given organic compound is the **Carbolamine Reaction**.
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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-1
  1. Tertiary butyl amine is a-

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  2. The correct set of the products obtained in the following reactions ...

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  3. Which one of the following tests can be used to identify primary ami...

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  4. D,C and D in the sequence are :

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  5. Lowest boiling point will be of the compound-

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  6. Identify B, X and R respectively in the following sequence of reaction...

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  7. Which product is a Schiff's base :-

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  8. A+CS(2)+HgCl(2) give C(2)H(5)-N=C=S. Thus compound A is :-

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  9. The end product of the reaction, Ethyl amine overset(HNO(2))rarr(A)o...

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  10. In the reaction sequence :- Aoverset(SnCl(2)//HCl)rarrBunderset(0^(@))...

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  11. Methylamine on treatment with chloroform and ethanolic caustic alkal...

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  12. Which of the following is used as a solvent in the Friedel-Crafts re...

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  13. CH(3)CH(2)CONH(2)underset(Br(2))overset(NaOH)rarrA Aqueous solution ...

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  14. Hinsber's reagent is used to distinguish between

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  15. Reactants of reaction -I are : CH(3)CONH(2),KOH,Br(2) Reactants of r...

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  16. Which of the following amine will not respond to carbylamine reactio...

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  17. (a) CH3 CONH2 +KOH +Br2 (b ) CH3 COOH + soda lime (c ) C...

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  18. Which of the following reagent can be used to convert benzene diazoniu...

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  19. Hofmann's method to separate amines in a mixture uses the reagent:-

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  20. Which of the following compounds will dissolve in an alkali sol...

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