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Identify B, X and R respectively in the ...

Identify B, X and R respectively in the following sequence of reactions
`C_(2)H_(5)MgBroverset(ClCN)rarrAoverset(H_(3)O^(+))rarrB`,
`CH_(3)COCH_(3)underset(NaOH)overset(I_(2))rarrXoverset(Ag)rarrY`
`C_(6)H_(5)NH_(2)underset(HCl)overset(NaNO_(2))rarrPoverset(CuCN)rarrQoverset(+4H)rarrR`

A

`C_(2)H_(5)COOH, CHI_(3),C_(6)H_(5)CH_(2)NH_(2)`

B

`C_(2)H_(5)COOH, CH_(3)I, C_(6)H_(5)COOH`

C

`C_(2)H_(5)CH_(2)NH_(2), CH_(3I, C_(6)H_(5)COOH`

D

`C_(2)H_(5)COOH, C_(2)H_(5)I, C_(6)H_(5)CONH_(2)``C_(2)H_(5)COOH, C_(2)H_(5)I, C_(6)H_(5)CONH_(2)`

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The correct Answer is:
To identify the compounds B, X, and R in the given sequence of reactions, let's analyze each step carefully. ### Step 1: Identify Compound A The first reaction involves ethyl magnesium bromide (C2H5MgBr) reacting with acetonitrile (ClCN). This reaction is a Grignard reaction leading to the formation of a nitrile. - **Reaction**: \[ C_2H_5MgBr + ClCN \rightarrow C_2H_5CN \quad (A) \] - **Product A**: Ethyl cyanide (C2H5CN) ### Step 2: Identify Compound B The next step involves the hydrolysis of compound A (C2H5CN) using acid (H3O+). This reaction converts the nitrile into a carboxylic acid. - **Reaction**: \[ C_2H_5CN + H_3O^+ \rightarrow C_2H_5COOH \quad (B) \] - **Product B**: Ethanoic acid (C2H5COOH) ### Step 3: Identify Compound X The next reaction involves acetone (CH3COCH3) undergoing a haloform reaction in the presence of iodine (I2) and sodium hydroxide (NaOH). This reaction produces methyl iodide (CH3I). - **Reaction**: \[ CH_3COCH_3 + I_2 + NaOH \rightarrow CH_3I \quad (X) \] - **Product X**: Methyl iodide (CH3I) ### Step 4: Identify Compound Y The reaction of methyl iodide (X) with silver (Ag) leads to the formation of acetylene (C2H2). - **Reaction**: \[ CH_3I + 6Ag \rightarrow C_2H_2 \quad (Y) \] - **Product Y**: Acetylene (C2H2) ### Step 5: Identify Compound P The next reaction involves aniline (C6H5NH2) reacting with sodium nitrite (NaNO2) in hydrochloric acid (HCl) to form benzene diazonium chloride (C6H5N2Cl). - **Reaction**: \[ C_6H_5NH_2 + NaNO_2 + HCl \rightarrow C_6H_5N_2Cl \quad (P) \] - **Product P**: Benzene diazonium chloride (C6H5N2Cl) ### Step 6: Identify Compound Q The diazonium salt (P) reacts with copper cyanide (CuCN) to form phenyl cyanide (C6H5CN). - **Reaction**: \[ C_6H_5N_2Cl + CuCN \rightarrow C_6H_5CN \quad (Q) \] - **Product Q**: Phenyl cyanide (C6H5CN) ### Step 7: Identify Compound R Finally, the reaction of phenyl cyanide (Q) with hydrogen (H2) in the presence of a catalyst (4H) leads to the formation of benzylamine (C6H5CH2NH2). - **Reaction**: \[ C_6H_5CN + 4H \rightarrow C_6H_5CH_2NH_2 \quad (R) \] - **Product R**: Benzylamine (C6H5CH2NH2) ### Summary of Identifications - **B**: Ethanoic acid (C2H5COOH) - **X**: Methyl iodide (CH3I) - **R**: Benzylamine (C6H5CH2NH2)
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ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-1
  1. D,C and D in the sequence are :

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  2. Lowest boiling point will be of the compound-

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  3. Identify B, X and R respectively in the following sequence of reaction...

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  4. Which product is a Schiff's base :-

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  5. A+CS(2)+HgCl(2) give C(2)H(5)-N=C=S. Thus compound A is :-

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  6. The end product of the reaction, Ethyl amine overset(HNO(2))rarr(A)o...

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  7. In the reaction sequence :- Aoverset(SnCl(2)//HCl)rarrBunderset(0^(@))...

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  8. Methylamine on treatment with chloroform and ethanolic caustic alkal...

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  9. Which of the following is used as a solvent in the Friedel-Crafts re...

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  10. CH(3)CH(2)CONH(2)underset(Br(2))overset(NaOH)rarrA Aqueous solution ...

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  11. Hinsber's reagent is used to distinguish between

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  12. Reactants of reaction -I are : CH(3)CONH(2),KOH,Br(2) Reactants of r...

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  13. Which of the following amine will not respond to carbylamine reactio...

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  14. (a) CH3 CONH2 +KOH +Br2 (b ) CH3 COOH + soda lime (c ) C...

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  15. Which of the following reagent can be used to convert benzene diazoniu...

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  16. Hofmann's method to separate amines in a mixture uses the reagent:-

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  17. Which of the following compounds will dissolve in an alkali sol...

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  18. The number of resonating structures of aniline is :-

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  19. C(7)H(9)N has how many isomeric forms that contain a benzene ring

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  20. The reaction of RCONH(2) with a mixture of Br(2) and aqueous KOH gives...

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