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The number of resonating structures of a...

The number of resonating structures of aniline is :-

A

2

B

3

C

4

D

5

Text Solution

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The correct Answer is:
To determine the number of resonating structures of aniline, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Structure of Aniline**: Aniline is an aromatic amine with the formula C6H5NH2. Its structure consists of a benzene ring (C6H5) attached to an amino group (NH2). 2. **Identify the Delocalization of Electrons**: In aniline, the lone pair of electrons on the nitrogen atom can participate in resonance with the π electrons of the benzene ring. This delocalization is key to forming different resonating structures. 3. **Draw the First Resonating Structure**: The first structure is the basic structure of aniline where the nitrogen atom has a lone pair of electrons and is connected to the benzene ring. 4. **Form the Second Resonating Structure**: In the second structure, the lone pair on the nitrogen can be used to form a double bond with the carbon atom of the benzene ring. This creates a positive charge on the nitrogen atom. 5. **Draw the Third Resonating Structure**: In the third structure, the double bond can shift to another carbon atom in the benzene ring, while the positive charge remains on the nitrogen. 6. **Continue with Additional Resonating Structures**: Repeat the process of shifting the double bond and the positive charge to different carbon atoms in the benzene ring. Each time you shift the double bond, you create a new resonating structure. 7. **Count All Unique Resonating Structures**: After drawing all possible unique structures, count them. For aniline, you will find that there are a total of five distinct resonating structures. ### Final Answer: The number of resonating structures of aniline is **5**. ---
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Knowledge Check

  • Resonating structures of molecules have :

    A
    identical bonding
    B
    different bonding
    C
    identical arragement of atoms and nearly same energies
    D
    the different number of paired and unpaired electrons
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