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Consider the following reaction , C(6)...

Consider the following reaction ,
`C_(6)H_(5)NH_(2)+CHCl_(3)+KOHoverset(Delta)rarr(A)overset(H^(+)//H_(2)O)rarr(B)+(C)`
The compounds (B) and (C) are :-

A

`C_(6)H_(5)COOH` and `NH_(3)` respectively

B

`C_(6)H_(5)NH_(2)` and `HCOOH` respectively

C

`C_(6)H_(5)NH_(2)` and `H_(2)O` respectively

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given reaction step by step, we will analyze the reactants and the processes involved. ### Step 1: Identify the reactants The reactants provided are: - Aniline (C₆H₅NH₂) - Chloroform (CHCl₃) - Potassium hydroxide (KOH) ### Step 2: Understand the reaction conditions The reaction is conducted under heating conditions (Δ), and KOH is used in alcoholic form. This indicates that we are likely dealing with a carbylamine reaction. ### Step 3: Carbylamine reaction When aniline reacts with chloroform and KOH, it undergoes a carbylamine reaction. The product formed in this step is phenylisocyanide (or phenylcarbamine), which is represented as (A): - **A** = C₆H₅N=C=O (Phenylisocyanide) ### Step 4: Hydrolysis of the product Next, the product (A) undergoes hydrolysis in the presence of H⁺ and H₂O. The hydrolysis of phenylisocyanide leads to the formation of two products: 1. Aniline (C₆H₅NH₂) 2. Formic acid (HCOOH) ### Step 5: Identify the final products Thus, the compounds (B) and (C) formed from the hydrolysis of (A) are: - **B** = C₆H₅NH₂ (Aniline) - **C** = HCOOH (Formic acid) ### Final Answer The compounds (B) and (C) are: - **B** = Aniline (C₆H₅NH₂) - **C** = Formic acid (HCOOH) ---
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