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Diazonium salt formation and coupling re...

Diazonium salt formation and coupling reaction: When a reaction mixture of phenyl amine and nitrous acid is kept below `10^(@)C`, a diazonium salt is formed. This reaction is called diazotization reaction.

The diazonium ion, `-N_(2)^(+)`, is rather unstable and decomposes readily to nitrogen. However, delocalization of the diazonium from `pi-`bond electron over a benzene ring phenyl diazonium sufficiently for it to form at low temperature. The phenyl diazonium ion behaves as an electrophile, and will attack another arene molecule such as phenol. Electrophilic subsitiution takes at the 4 position, producing 4-hydroxy phenyl azobenzene. The reaction is known as coupling reaction.

The compound formed is an energetically stable, yellow azo dye (the azo group is `-N=N-`) The stability is due to extensive delocalisation of electrons via the nitrogen- nitrogen double bonds.
The product which is a red azodye obtained on reacting benzene diazonium chloride with one of the following compounds :

A

B

C

D

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The correct Answer is:
B
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Diazonium salt formation and coupling reaction: When a reaction mixture of phenyl amine and nitrous acid is kept below 10^(@)C , a diazonium salt is formed. This reaction is called diazotization reaction. The diazonium ion, -N_(2)^(+) , is rather unstable and decomposes readily to nitrogen. However, delocalization of the diazonium from pi- bond electron over a benzene ring phenyl diazonium sufficiently for it to form at low temperature. The phenyl diazonium ion behaves as an electrophile, and will attack another arene molecule such as phenol. Electrophilic subsitiution takes at the 4 position, producing 4-hydroxy phenyl azobenzene. The reaction is known as coupling reaction. The compound formed is an energetically stable, yellow azo dye (the azo group is -N=N- ) The stability is due to extensive delocalisation of electrons via the nitrogen- nitrogen double bonds. Benzene diazonium chloride on reaction with phenol in weakly basic medium gives :

Diazonium salt formation and coupling reaction: When a reaction mixture of phenyl amine and nitrous acid is kept below 10^(@)C , a diazonium salt is formed. This reaction is called diazotization reaction. The diazonium ion, -N_(2)^(+) , is rather unstable and decomposes readily to nitrogen. However, delocalization of the diazonium from pi- bond electron over a benzene ring phenyl diazonium sufficiently for it to form at low temperature. The phenyl diazonium ion behaves as an electrophile, and will attack another arene molecule such as phenol. Electrophilic subsitiution takes at the 4 position, producing 4-hydroxy phenyl azobenzene. The reaction is known as coupling reaction. The compound formed is an energetically stable, yellow azo dye (the azo group is -N=N- ) The stability is due to extensive delocalisation of electrons via the nitrogen- nitrogen double bonds. The azo dye obtained on reacting 4-aminophenol with nitrous acid (in dilute hydrochloric acid) below 10^(@)C and coupling the resulting diazonium salt with phenol is :

Diazonium salt , the reaction is known as

the reduction on benzene diazonium chloride with SnCl_2 and HCI acid gives :

Which of the following reagent can be used to convert benzene diazonium chloride to phenol?

Amine oxide , when heated , forms alkene. This reaction is called

Yellow dye can be prepared by a coupling reaction of benzene diazonium chloride in acid medium with x. Identify X from the following

At what pH phenol reacts with benzene diazonium chIoride to give coupling product?

On heating aqueous solution of benzene diazonium chloride, which is formed

Knowledge Check

  • The compound which will radily couple with benzene diazonium chloride is :

    A
    benzoic acid
    B
    phenol
    C
    benzene
    D
    benzaldehyde
  • ALLEN-ALKENE, ALKANE & ALKYNE -EXERCISE-3
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