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Statement-1 : The groundstate configurat...

Statement-1 : The groundstate configuration of Cr is [Ar] `3d^(5) 4s^(1)`
Statement-2 : The energy of atom is lesser in `3d^(5)4s^(1)` configuration compared to `3d^(4)4s^(2)` configuration.

A

Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.

B

Staterment-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.

C

Statement-1 is true, statement-2 is false.

D

Statement-1 is false, statement-2 is true.

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AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both statements regarding the ground state electron configuration of chromium (Cr) and the energy levels associated with different configurations. ### Step 1: Analyze Statement-1 The ground state configuration of chromium (Cr) is given as [Ar] `3d^(5) 4s^(1)`. - Chromium has an atomic number of 24, which means it has 24 electrons. - The expected electron configuration based on the Aufbau principle would be [Ar] `3d^(4) 4s^(2)`. However, chromium is an exception to this rule. - The actual configuration is [Ar] `3d^(5) 4s^(1)` because having a half-filled d-subshell (3d) provides extra stability due to symmetry and exchange energy. ### Step 2: Analyze Statement-2 The second statement claims that the energy of the atom is lesser in the `3d^(5) 4s^(1)` configuration compared to the `3d^(4) 4s^(2)` configuration. - A half-filled d-subshell (3d) is more stable than a partially filled one (3d with 4 electrons). - The stability arises from the symmetrical distribution of electrons and the maximization of exchange energy, which lowers the overall energy of the atom. - Therefore, the configuration `3d^(5) 4s^(1)` is indeed lower in energy and more stable than `3d^(4) 4s^(2)`. ### Conclusion Both statements are correct: - Statement-1 is correct as it accurately describes the ground state configuration of chromium. - Statement-2 is also correct as it explains the stability and lower energy associated with the `3d^(5) 4s^(1)` configuration compared to `3d^(4) 4s^(2)`. Thus, the answer is that both statements are true and Statement-1 provides a correct explanation for Statement-2. ### Final Answer Both statements are true, and Statement-1 is the correct explanation for Statement-2. ---
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ALLEN-QUANTUM NUMBER & PERIODIC TABLE-EXERCISE
  1. Choose the s-block element from the following:

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  2. Among the following which species is/are paramagnetic (i) Sr^(2+) ...

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  3. It each orbital can hold a maximum of three electrons, the number of e...

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  4. Which of the following clement has highest metallic character

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  5. The electronic configuration of an clement is 1s^(2), 2s^(2), 2p^(6), ...

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  6. the number of d- electrons in Mn^(2+) is equal to that of :

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  7. Which of the following is correct order of EA.

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  8. Which of the following are correct

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  9. If Aufbau's principle and Hund's rule were not followed.

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  10. In halogen, which of the following properties increase from iodine to ...

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  11. Amongst the following statements, which is/are correct?

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  12. Select the correct statements (s)

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  13. Statement-1 : The groundstate configuration of Cr is [Ar] 3d^(5) 4s^(1...

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  14. Assertion: The first ionisation energy of Be is greater than that of B...

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  15. Statement-1 : IE(1) ofN is greater than 0 . Statement-2: N-atom is b...

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  16. Statement-1 : First electron gain enthalpy is alway -ve for an element...

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  17. Statement-1: Ionization potential of Sn is less than Pb. Statement-2...

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  18. Statement-1 : Electron gain enthalpy of Cl is largest in periodic tabl...

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  19. Match the column :

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  20. Minimum number of electrons having m(s)=(-1/2) in Cr is ""

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