Home
Class 12
CHEMISTRY
The most intense line in the Brackett se...

The most intense line in the Brackett series of the spectrum of atomic hydrogen is the transition :-

A

`n_(2)=ooton_(1)=1`

B

`n_(2)=8ton_(1)=4`

C

`n_(2)=ooton_(1)=4`

D

`n_(2)=4ton_(1)=3`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the most intense line in the Brackett series of the spectrum of atomic hydrogen, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Series**: The hydrogen spectrum consists of several series: Lyman, Balmer, Paschen, Brackett, and Pfund. For the Brackett series, the transitions occur from higher energy levels to n=4. 2. **Define n1 and n2**: In the Brackett series, the lower energy level (n1) is 4. The upper energy level (n2) can be any integer greater than 4 (i.e., n2 = 5, 6, 7, ...). 3. **Determine the Most Intense Line**: The intensity of spectral lines is related to the energy difference between the two levels involved in the transition. The energy of the transition can be calculated using the formula: \[ E = R_H \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where \( R_H \) is the Rydberg constant. 4. **Maximize Energy**: To find the most intense line, we need to maximize the energy difference. The energy difference is maximized when \( n_2 \) is as large as possible, specifically when \( n_2 \) approaches infinity. This is because: \[ \frac{1}{n_2^2} \to 0 \text{ as } n_2 \to \infty \] Therefore, the energy becomes: \[ E = R_H \left( \frac{1}{4^2} - 0 \right) = R_H \left( \frac{1}{16} \right) \] 5. **Conclusion**: The most intense line in the Brackett series occurs when \( n_2 \) approaches infinity. Thus, the transition that corresponds to the most intense line in the Brackett series is: \[ n_1 = 4 \text{ and } n_2 = \infty \] ### Final Answer: The most intense line in the Brackett series of the spectrum of atomic hydrogen is the transition from \( n_2 = \infty \) to \( n_1 = 4 \). ---
Promotional Banner

Topper's Solved these Questions

  • ALKYL AND ARYL HALIDE

    ALLEN|Exercise EXERCISE-05 (B)|35 Videos
  • BASIC INTRODUCTION AND NOMENCLATURE

    ALLEN|Exercise MCQ|12 Videos

Similar Questions

Explore conceptually related problems

The shortest wavelength spectral line in the brackett series of the spectrum of atomic hydrogen is the transition :

The third line of the Balmer series, in the emission spectrum of the hydrogen atom, is due to the transition from the

The third line of the Balmer series, in the emission spectrum of the hydrogen atom, is due to the transition from the

The first emission line in the atomic spectrum of hydrogen in the Balmer series appears at

Which transitions are responsible for the occurrence of Brackett series in the spectrum of hydrogen?

In the spectrum of singly ionized helium , the wavelength of a line abserved is almost the same as the first line of Balmer series of hydrogen . It is due to transition of electron

In the spectrum of singly ionized helium , the wavelength of a line abserved is almost the same as the first line of Balmer series of hydrogen . It is due to transition of electron from n_(1) = 6 to n_(2) = ^(''**'') . What is the value of (''**'') .

The spectral series of the hydrogen spectrum that lies in the ultraviolet region is the

The Lyman series of hydrogen spectrum lies in the region :

The shortest wavelength of the Brackett series of a hydrogen-like atom (atomic number of Z ) is the same as the shortest wavelength of the Balmer series of hydrogen atom. The value of z is

ALLEN-Atomic Structure-All Questions
  1. In how many elements does the electron have the quantum number of n =...

    Text Solution

    |

  2. For principle quantum number n=4,the total number of orbitals having l...

    Text Solution

    |

  3. Choose the wrong one on the basis of Bohr 's theory :-

    Text Solution

    |

  4. In which transition, one quantum of energy is emitted - (a). n=4 rarr...

    Text Solution

    |

  5. If the value of principal quantum number is 4 , the possible values fo...

    Text Solution

    |

  6. If the value of E=-78.4 "kcal//mol", the order of the orbit in hydroge...

    Text Solution

    |

  7. The ratio of energy of the electron in ground state of hydrogen to the...

    Text Solution

    |

  8. The most intense line in the Brackett series of the spectrum of atomic...

    Text Solution

    |

  9. Five valence electrons of .^(15)P re labelled as If the spin ...

    Text Solution

    |

  10. If kinetic energy of a proton is increased nine times the wavelengt...

    Text Solution

    |

  11. If first ionization potential of an atom is 16 V, then the first excit...

    Text Solution

    |

  12. The angular momentum J of the electron in a hydrogen atom is proportio...

    Text Solution

    |

  13. Which one of the following sets of quantum numbers represents an impos...

    Text Solution

    |

  14. An electron is present in 4 f sub - shell . The possible values of azi...

    Text Solution

    |

  15. How many electrons in calcium have l = 0 ?

    Text Solution

    |

  16. For n = 4 , which of the following is true

    Text Solution

    |

  17. An atom has 35 nucleons and has atomis number equal to 17 . The number...

    Text Solution

    |

  18. The maximum number of electrons in p-orbital with n = 6, m = 0 is

    Text Solution

    |

  19. A dye absorbs a photon of wavelength lamda and re-emits the same energ...

    Text Solution

    |

  20. The number of photons of light having wave number 'x' in 10 J of energ...

    Text Solution

    |