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When a catalyst increases the rate of ch...

When a catalyst increases the rate of chemical reaction the rate constant :-

A

Increases

B

Decreases

C

Remains constant

D

Becomes infinite

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question "When a catalyst increases the rate of chemical reaction, the rate constant:", we can follow these steps: ### Step 1: Understand the Role of a Catalyst A catalyst is a substance that increases the rate of a chemical reaction without being consumed in the process. It achieves this by lowering the activation energy required for the reaction to occur. **Hint:** Remember that catalysts do not change the overall energy of the reaction; they only provide an alternative pathway with lower activation energy. ### Step 2: Define Rate Constant The rate constant (k) is a proportionality constant that relates the rate of a reaction to the concentrations of the reactants. The rate law for a reaction can be expressed as: \[ \text{Rate} = k \cdot [\text{Reactants}]^n \] where \( n \) is the order of the reaction. **Hint:** The rate constant is specific to a given reaction at a particular temperature. ### Step 3: Relate Activation Energy and Rate Constant According to the Arrhenius equation: \[ k = A \cdot e^{-\frac{E_a}{RT}} \] where: - \( k \) = rate constant - \( A \) = pre-exponential factor - \( E_a \) = activation energy - \( R \) = gas constant - \( T \) = temperature From this equation, we can see that the rate constant \( k \) is inversely proportional to the activation energy \( E_a \). **Hint:** A lower activation energy means that more molecules have enough energy to react, which increases the rate constant. ### Step 4: Analyze the Effect of a Catalyst When a catalyst is introduced, it lowers the activation energy \( E_a \). As a result, according to the Arrhenius equation, the rate constant \( k \) increases. **Hint:** Focus on how the catalyst affects the energy barrier for the reaction. ### Step 5: Conclusion Since the catalyst increases the rate of the reaction by decreasing the activation energy, the rate constant \( k \) must also increase. **Final Answer:** The rate constant increases when a catalyst increases the rate of a chemical reaction. **Correct Option:** Increases (Option 1)
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ALLEN-SURFACE CHEMISTRY -ASSERTION & REASO
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  7. Assertion :- Lyophilic sol is more stable than lyophobic sol. Reaso...

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  9. Assertion :- In case of chemical adsorption, (x)/(m) first increase th...

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  12. Assertion :- Zeolite is shape selective catalyst. Reason :- Size of ...

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  13. Assertion :- Lyophilic sol coagulate by adding other solvent. Reason...

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  15. Assertion :- During physical adsorption multimolecular layers are form...

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