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The dipole moment of H(2)O(2) is 2.1 D. ...

The dipole moment of `H_(2)O_(2)` is 2.1 D. this indicates that the structure of `H_(2)O_(2)` is :

A

Linear

B

Non-linear

C

Symmetrical

D

None

Text Solution

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The correct Answer is:
To determine the structure of hydrogen peroxide (H₂O₂) based on its dipole moment of 2.1 D, we can follow these steps: ### Step 1: Understand the Dipole Moment The dipole moment is a measure of the separation of positive and negative charges in a molecule. A higher dipole moment indicates that the molecule has a significant difference in electronegativity between the bonded atoms and/or an asymmetrical shape. **Hint:** Remember that a dipole moment indicates the presence of polar bonds and the overall shape of the molecule. ### Step 2: Draw the Structure of H₂O₂ Hydrogen peroxide has the following structure: - Two oxygen atoms are bonded to each other. - Each oxygen atom is also bonded to one hydrogen atom. The Lewis structure can be represented as: ``` H H \ / O - O ``` **Hint:** Visualizing the molecular structure can help in understanding the spatial arrangement of atoms. ### Step 3: Analyze the Geometry The molecular geometry of H₂O₂ can be analyzed by considering the bond angles and the arrangement of atoms: - The bond angle between the O-O-H and O-H bonds is approximately 101.6 degrees, and the O-O bond has a bond angle of about 90.2 degrees. - This indicates that the molecule does not have a linear shape. **Hint:** Look for bond angles and the arrangement of atoms to determine if the structure is linear or non-linear. ### Step 4: Determine Symmetry To assess whether the structure is symmetrical or not: - The arrangement of the hydrogen and oxygen atoms is not symmetrical because the molecule has different atoms (H and O) and the bond angles are not equal. - Therefore, H₂O₂ is considered to be an unsymmetrical molecule. **Hint:** Symmetry can often be assessed by checking if the molecule can be divided into two identical halves. ### Step 5: Conclusion Based on the analysis: - The dipole moment of 2.1 D suggests that H₂O₂ is a polar molecule. - The structure is non-linear due to the angles and arrangement of atoms. - It is also unsymmetrical because of the different atoms and bond angles. Thus, the correct answer is that the structure of H₂O₂ is non-linear. **Final Answer:** The structure of H₂O₂ is non-linear (Option B). ---

To determine the structure of hydrogen peroxide (H₂O₂) based on its dipole moment of 2.1 D, we can follow these steps: ### Step 1: Understand the Dipole Moment The dipole moment is a measure of the separation of positive and negative charges in a molecule. A higher dipole moment indicates that the molecule has a significant difference in electronegativity between the bonded atoms and/or an asymmetrical shape. **Hint:** Remember that a dipole moment indicates the presence of polar bonds and the overall shape of the molecule. ### Step 2: Draw the Structure of H₂O₂ ...
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