Home
Class 12
CHEMISTRY
Assertion : Molar mass of D(2)O is more ...

Assertion : Molar mass of `D_(2)O` is more than than of protium oxide.
Reason : Boiling point of protium oxide is higher than that of `D_(2)O`.

A

If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.

B

If both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.

C

If Assertion is True but the Reason is False.

D

If both Assertion & Reason are False.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we will analyze both the assertion and the reason step by step. ### Step 1: Analyze the Assertion **Assertion:** The molar mass of D₂O is more than that of protium oxide (H₂O). - **Calculation of Molar Mass of D₂O:** - D₂O (Deuterium oxide) consists of 2 deuterium atoms and 1 oxygen atom. - Molar mass of deuterium (D) = 2 g/mol. - Molar mass of oxygen (O) = 16 g/mol. - Therefore, molar mass of D₂O = (2 × 2) + 16 = 4 + 16 = 20 g/mol. - **Calculation of Molar Mass of H₂O:** - H₂O (Protium oxide) consists of 2 hydrogen atoms and 1 oxygen atom. - Molar mass of hydrogen (H) = 1 g/mol. - Therefore, molar mass of H₂O = (2 × 1) + 16 = 2 + 16 = 18 g/mol. - **Comparison:** - Molar mass of D₂O = 20 g/mol. - Molar mass of H₂O = 18 g/mol. - Since 20 g/mol > 18 g/mol, the assertion is **true**. ### Step 2: Analyze the Reason **Reason:** The boiling point of protium oxide (H₂O) is higher than that of D₂O. - **Boiling Points:** - The boiling point of H₂O (protium oxide) is approximately 100°C. - The boiling point of D₂O (deuterium oxide) is approximately 101.4°C. - **Comparison:** - Since the boiling point of D₂O (101.4°C) is higher than that of H₂O (100°C), the reason is **false**. ### Conclusion - The assertion is true, but the reason is false. Therefore, the correct option is: **Option C: Assertion is true but the reason is false.** ---
Promotional Banner

Topper's Solved these Questions

Similar Questions

Explore conceptually related problems

Boiling point of phosphine is higher than that of ammonia.

Boiling point of ethyl chloride is higher than that of ethyl bromide.

D_2O is more polar than H_2O.

Protium oxide is the name given to D_2O.

Why the boiling point of ethyl bromide is higher than that of ethyl chloride?

Boiling point of dimethyl ether is ul("higher than that of the ethanol.")

The boiling point of bromoethane is higher than that of chloroethane. Explain.

The boiling point of C Cl_(4) higher than that of CHCl_(3) because :

Assertion : Boiling point of ethanol is higher than that of propane. Reason : Molecular mass of ethanol is higher than propane.

Solubility of CO_(2) is ________ times higher than that of O_(2)

ALLEN-HYDROGEN-EXERCISE-5
  1. Assertion : Cu react with HCl & form H(2) gas Reason : Cu lies above...

    Text Solution

    |

  2. Assertion (A) Decomposition of H(2)O(2) is a disproportionation reacti...

    Text Solution

    |

  3. Assertion (A) Hydrogen combines with order elements by losing, gaining...

    Text Solution

    |

  4. Assertion (A) H(2)O(2) is not stored in glass bottles. Reason (R ) ...

    Text Solution

    |

  5. Assertion : Ferricyanide ion oxidises H(2)O(2) to H(2)O. Reason : Ox...

    Text Solution

    |

  6. Assertion (A): The colour of old lead painting can be restored by wash...

    Text Solution

    |

  7. Assertion : Water has a boiling point higher than that of H(2)S. Rea...

    Text Solution

    |

  8. Assertion : H(2)O(2) react with PbS to form PbSO(4). Reason : H(2)O(...

    Text Solution

    |

  9. Assertion : Molar mass of D(2)O is more than than of protium oxide. ...

    Text Solution

    |

  10. Assertion (A) The O-O bond length in H(2)O(2) is shorter than that in ...

    Text Solution

    |

  11. Asseriton : Hard Water is not fit for washing clothes. Reason : It c...

    Text Solution

    |

  12. Assertion : Rate of reaction CD(4)+Cl(2)rarr" Slow "CH(4)+C...

    Text Solution

    |

  13. Assertion : Hydrogen cannot be prepared in laboratory. Reason : Hydr...

    Text Solution

    |

  14. Assertion : Ortho and Para dihydrogen are nuclear spin isomers. Reas...

    Text Solution

    |

  15. Assertion : Saline hydrides are non volatile, non conducting & crystal...

    Text Solution

    |

  16. Assertion : Temporary hardness can be removed by boiling. Reason : O...

    Text Solution

    |

  17. Assertion : Sulphur is oxidised by H(2)O(2) in presence of Fe(III) R...

    Text Solution

    |