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At anode in the electrolysis of fused Na...

At anode in the electrolysis of fused `NaCl`:

A

`Na^(+)` is oxidised

B

`CI^(-1)` is oxidised

C

`CI^(-)` is reduced

D

`Na^(+)` is reduced

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AI Generated Solution

The correct Answer is:
To solve the question regarding the electrolysis of fused NaCl and identify what occurs at the anode, we can follow these steps: ### Step 1: Understand the Process of Electrolysis Electrolysis involves the decomposition of a compound into its elements by passing an electric current through it. In the case of fused NaCl, we are dealing with sodium ions (Na⁺) and chloride ions (Cl⁻). **Hint:** Remember that during electrolysis, oxidation occurs at the anode and reduction occurs at the cathode. ### Step 2: Identify the Ions Present In fused NaCl, the dissociation can be represented as: - NaCl → Na⁺ + Cl⁻ Here, Na⁺ is the cation and Cl⁻ is the anion. **Hint:** Write down the ions formed when NaCl is melted to understand what will be present during electrolysis. ### Step 3: Determine the Reactions at the Electrodes At the anode (positive electrode), oxidation occurs. This means that the anion (Cl⁻) will lose electrons. The half-reaction can be written as: - 2Cl⁻ → Cl₂ + 2e⁻ At the cathode (negative electrode), reduction occurs. The cation (Na⁺) will gain electrons: - Na⁺ + e⁻ → Na **Hint:** Recall that oxidation involves the loss of electrons, while reduction involves the gain of electrons. ### Step 4: Identify the Product at the Anode From the half-reaction at the anode, we see that chloride ions (Cl⁻) are oxidized to form chlorine gas (Cl₂). Therefore, the product formed at the anode during the electrolysis of fused NaCl is chlorine gas. **Hint:** Focus on the changes in oxidation states to determine which species is oxidized. ### Step 5: Conclusion Thus, during the electrolysis of fused NaCl, chlorine gas is produced at the anode. **Final Answer:** At the anode in the electrolysis of fused NaCl, chlorine (Cl₂) is produced.
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ALLEN-S-BLOCK ELEMENTS -EXERCISE
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  2. Thermal stability of BaCO(3), CaCO(3), and MgCO(3) is

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  3. At anode in the electrolysis of fused NaCl:

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  4. One mole of magnesium nitride on reaction with an excess of water give...

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  5. Which alkali metal on flame test given red violet colour

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  6. In presence of iron, alkali metal react with liquid ammonia and form

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  7. The order of ionic conductance of alkali metal ions in their aqueous s...

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  8. Photoelectric effect is the maximum in

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  9. Which of the following carbides on treatment with water give methane ...

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  10. When a standard solution of NaOH is left in air for a few hours:

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  11. The ionic mobility of alkali metal ions in aqueous solution is maximum...

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  12. Which is used in purification of air in the space craft.

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  13. Which of the following alkaline earth metal suphate salt is the least ...

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  14. In aqueous solution, the largest ion is :

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  15. The correct order of ionic character of oxides of alkali earth metal:-

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  16. KO2 (potassium super oxide) is used in space and submarines because it...

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  17. Compounds of alkaline earth metals are generally less soluble in water...

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  18. The melting point of NaCl is high because:-

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  19. The products obtained on heating LiNO(3) will be

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  20. Which of the following on thermal decomposition yields a basic as well...

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