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Increasing order of stability of- I. K...

Increasing order of stability of-
I. `K_(2)CO_(3)` II. `MgCO_(3)` III `Na_(2)CO_(3)`

A

`I lt II lt III`

B

`II lt III lt I`

C

`II lt I lt III`

D

`I lt III lt II`

Text Solution

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The correct Answer is:
To determine the increasing order of stability for the carbonates \( K_2CO_3 \), \( MgCO_3 \), and \( Na_2CO_3 \), we need to analyze the thermal stability of these compounds based on the degree of polarization of the cations involved. ### Step-by-Step Solution: 1. **Understanding Thermal Stability**: - Thermal stability refers to the ability of a compound to withstand heat without decomposing. For carbonates, this often involves the breakdown into oxides and carbon dioxide upon heating. 2. **Degree of Polarization**: - The thermal stability of carbonates is inversely related to the degree of polarization of the cation. A higher degree of polarization indicates a more covalent character, which leads to lower thermal stability. 3. **Identifying the Cations**: - The cations in question are \( K^+ \) (potassium), \( Na^+ \) (sodium), and \( Mg^{2+} \) (magnesium). - Potassium and sodium are alkali metals, while magnesium is an alkaline earth metal. 4. **Comparing Cation Sizes**: - As we move down the group in the periodic table, the size of the cations increases. Larger cations have a lower charge density, which results in less polarization. - Therefore, \( K^+ \) is larger than \( Na^+ \), and both are larger than \( Mg^{2+} \). 5. **Covalent vs Ionic Character**: - According to Fajans' rules, larger cations (like \( K^+ \)) will have more ionic character and less covalent character compared to smaller cations (like \( Mg^{2+} \)). - Thus, \( K^+ \) has the least covalent character, followed by \( Na^+ \), and \( Mg^{2+} \) has the most covalent character. 6. **Determining Stability Order**: - Since \( K^+ \) has the least covalent character, \( K_2CO_3 \) will be the most thermally stable. - Next, \( Na_2CO_3 \) will have moderate stability, and finally, \( MgCO_3 \) will be the least stable due to its higher covalent character. 7. **Final Order of Stability**: - The increasing order of stability is: \[ MgCO_3 < Na_2CO_3 < K_2CO_3 \] ### Answer: The increasing order of stability is: \[ MgCO_3 < Na_2CO_3 < K_2CO_3 \]

To determine the increasing order of stability for the carbonates \( K_2CO_3 \), \( MgCO_3 \), and \( Na_2CO_3 \), we need to analyze the thermal stability of these compounds based on the degree of polarization of the cations involved. ### Step-by-Step Solution: 1. **Understanding Thermal Stability**: - Thermal stability refers to the ability of a compound to withstand heat without decomposing. For carbonates, this often involves the breakdown into oxides and carbon dioxide upon heating. 2. **Degree of Polarization**: ...
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ALLEN-S-BLOCK ELEMENTS -EXERCISE
  1. Which of the following releases 0.2 moles of hydrogen on hydrolysis-

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  2. On electrolysis of fused NaCl the final product is-

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  3. Increasing order of stability of- I. K(2)CO(3) II. MgCO(3) III Na(2)...

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  4. Which of the following has an unpaired electron in it

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  5. A compound which on hydrolysis releases ammonia is-

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  6. The metal ion which does not give any flame colouration is-

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  7. Salt of which alkali metals exists as hydrated salt ?

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  8. NaHCO(3) can be used to-

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  9. Strong reductant in IIA and IA group is-

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  10. The sulphate of which metal does not form alum:-

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  11. The electrolytic reduction process is used for alkali metals, because:...

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  12. Which statement is false for an element, having 2,8,8,2 electronic con...

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  13. Mostly metals are hard, but metals of Ist A group are soft, because:-

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  14. The normal dehydrating agent, which used in a laboratories:-

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  15. What is the decreasing order of standard oxidation potential of K,Ca a...

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  16. Which statement will be true for solution, when Ba is dissolved in amm...

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  17. Alkaline earth metals show:-

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  18. In K,Rb and Cs, the decreasing order of reducing power in gaseous stat...

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  19. Prefix 'Alkali' denotes for:-

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  20. Which of the following is the weakest base:-

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