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Li does resemble other alkali metals in ...

`Li` does resemble other alkali metals in following properties:

A

`Li_(2)CO_(3)` decomposes into oxides while other alkali carbonates are thermally stable

B

`LiCI` is predominatly covalent

C

`Li_(3)N` is stable

D

All

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The correct Answer is:
To solve the question regarding the properties of lithium (`Li`) that resemble other alkali metals, we will analyze each of the given options step by step. ### Step 1: Analyze the first option **Statement**: `Li2CO3` decomposes into oxides while other alkali carbonates are thermally stable. - **Explanation**: Lithium carbonate (`Li2CO3`) is unique among the alkali metal carbonates as it decomposes upon heating to form lithium oxide (`Li2O`) and carbon dioxide (`CO2`). This is in contrast to other alkali metal carbonates, which are generally stable and do not decompose easily under similar conditions. - **Reaction**: \[ \text{Li}_2\text{CO}_3 \xrightarrow{\text{heat}} \text{Li}_2\text{O} + \text{CO}_2 \] - **Conclusion**: This option is correct. ### Step 2: Analyze the second option **Statement**: `LiCl` is predominantly covalent. - **Explanation**: Lithium chloride (`LiCl`) exhibits covalent character due to the small size and high charge density of the lithium ion, which leads to significant polarization of the chloride ion. As a result, `LiCl` does not dissociate into ions in the molten state, making it non-conductive. It can also dissolve in non-polar solvents like ether, which is characteristic of covalent compounds. - **Conclusion**: This option is correct. ### Step 3: Analyze the third option **Statement**: `Li3N` is stable. - **Explanation**: Lithium nitride (`Li3N`) is indeed stable, and it is unique among the alkali metals as it is the only nitride formed by a group 1 element. Other alkali metals do not form stable nitrides. This stability is attributed to the strong ionic bonding in `Li3N`. - **Conclusion**: This option is correct. ### Step 4: Analyze the fourth option **Statement**: All of these. - **Explanation**: Since we have established that all the previous statements about lithium are correct, this option is also correct. - **Conclusion**: The correct answer is option 4, which states that all the properties mentioned are true for lithium. ### Final Answer The correct answer is **Option 4: All of these**. ---
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ALLEN-S-BLOCK ELEMENTS -EXERCISE
  1. In the reaction, M + CO(2) to MO(2) (superoixde) the metal M is :

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  2. Addition of NaOH on Zn^(2+) ion gives a white ppt. which on addition o...

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  3. Li does resemble other alkali metals in following properties:

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  4. Be and Al resemble in

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  5. The hydride which doesno't act as reducing agent is

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  6. The correct order of hydration energy of alkaline earth metal ions is

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  7. Na^(+) and Ag^(+) differ in

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  8. Magnesium powder burns in air to give :

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  9. Consider the following points : (a) Cs is the strongest reducing age...

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  10. Mg^(+2) does not form either preoxide or superoxidem because

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  11. The stability order of oxide, peroxide and superoxide of alkalimetal i...

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  12. Match list I with list II and choose the correct answer from the codes...

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  13. Alkali metals forms following compound

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  14. Which alkaline earth metal compound is volatile

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  15. Match the compound(s)/metal(s) in X with their uses in Y {:(X,Y),(A....

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  16. The reaction of sodium is highly exothermic with water. The rate of re...

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  17. Which of the following statement is not correct?

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  18. In between the metals A and B both form oxide but B also forms nitride...

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  19. When SiCl(4) vapours are passed over hot Mg, the products formed are

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  20. The metal X is prepared by the electrolysis of fused chloride. It reac...

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