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Be and Al resemble in...

Be and Al resemble in

A

Both become passive on reaction with `HNO_(3)` due to formation of oxide layer

B

Their chlorides are lewis acids

C

Hydroxides are soluble in alkali as well as in acid

D

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The correct Answer is:
To determine how beryllium (Be) and aluminum (Al) resemble each other, we can analyze the following aspects: ### Step-by-Step Solution: 1. **Reactivity with Nitric Acid**: - Both beryllium and aluminum react with nitric acid (HNO₃) to form their respective oxides and other products. - Beryllium reacts as follows: \[ 3 \text{Be} + 8 \text{HNO}_3 \rightarrow 3 \text{BeO} + 8 \text{NO} + 4 \text{H}_2\text{O} \] - Aluminum reacts as follows: \[ 2 \text{Al} + 6 \text{HNO}_3 \rightarrow 2 \text{Al(NO}_3\text{)}_3 + 3 \text{H}_2\text{O} \] - In both reactions, a protective oxide layer is formed, making both metals passive to further reaction with nitric acid. 2. **Lewis Acidity of Chlorides**: - The chlorides of both beryllium (BeCl₂) and aluminum (AlCl₃) act as Lewis acids. - A Lewis acid is defined as a substance that can accept an electron pair. - Both BeCl₂ and AlCl₃ have vacant orbitals that allow them to accept electrons, thus exhibiting Lewis acid behavior. 3. **Amphoteric Nature of Hydroxides**: - The hydroxides of both beryllium (Be(OH)₂) and aluminum (Al(OH)₃) are amphoteric. - This means they can react with both acids and bases: - For example, Be(OH)₂ can react with hydrochloric acid (HCl) and sodium hydroxide (NaOH): \[ \text{Be(OH)}_2 + 2 \text{HCl} \rightarrow \text{BeCl}_2 + 2 \text{H}_2\text{O} \] \[ \text{Be(OH)}_2 + 2 \text{NaOH} \rightarrow \text{Na}_2\text{Be(OH)}_4 \] - Similarly, Al(OH)₃ can react with both acids and bases. 4. **Conclusion**: - Therefore, beryllium and aluminum resemble in the following aspects: - Both become passive on reaction with nitric acid due to the formation of an oxide layer. - Their chlorides are Lewis acids. - Their hydroxides are amphoteric, being soluble in both acids and bases. ### Final Answer: Beryllium and aluminum resemble in: - Both become passive on reaction with nitric acid. - Their chlorides are Lewis acids. - Their hydroxides are amphoteric.
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ALLEN-S-BLOCK ELEMENTS -EXERCISE
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  2. Li does resemble other alkali metals in following properties:

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  3. Be and Al resemble in

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  4. The hydride which doesno't act as reducing agent is

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  5. The correct order of hydration energy of alkaline earth metal ions is

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  6. Na^(+) and Ag^(+) differ in

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  7. Magnesium powder burns in air to give :

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  8. Consider the following points : (a) Cs is the strongest reducing age...

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  9. Mg^(+2) does not form either preoxide or superoxidem because

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  10. The stability order of oxide, peroxide and superoxide of alkalimetal i...

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  11. Match list I with list II and choose the correct answer from the codes...

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  12. Alkali metals forms following compound

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  13. Which alkaline earth metal compound is volatile

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  14. Match the compound(s)/metal(s) in X with their uses in Y {:(X,Y),(A....

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  15. The reaction of sodium is highly exothermic with water. The rate of re...

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  16. Which of the following statement is not correct?

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  17. In between the metals A and B both form oxide but B also forms nitride...

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  18. When SiCl(4) vapours are passed over hot Mg, the products formed are

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  19. The metal X is prepared by the electrolysis of fused chloride. It reac...

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  20. Which of the following statement is not correct?

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