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{:(,"Compounds",,"O.N."),((A),KMn^(**)O(...

`{:(,"Compounds",,"O.N."),((A),KMn^(**)O_(4),(1),+4),((B),Ni^(**)(CO)_(4),(2),+7),((C),[Pt^(**)(NH_(3))Cl_(2)]Cl_(2),(3),0),((D),Na_(2)O_(2)^(**),(4),-1):}`
The correct code for the O.N. of asterisked atom would be:

A

`{:(A,B,C,D),(1,2,3,4):}`

B

`{:(A,B,C,D),(4,3,2,1):}`

C

`{:(A,B,C,D),(2,3,1,4):}`

D

`{:(A,B,C,D),(4,1,2,3):}`

Text Solution

AI Generated Solution

The correct Answer is:
To find the oxidation numbers of the specified atoms in the given compounds, we will analyze each compound step by step. ### Step 1: Determine the oxidation number of Mn in KMnO4 1. **Identify the oxidation states of other elements:** - Potassium (K) has an oxidation state of +1. - Oxygen (O) has an oxidation state of -2. Since there are 4 oxygen atoms, the total contribution from oxygen is \(4 \times (-2) = -8\). 2. **Set up the equation:** \[ \text{Oxidation state of K} + \text{Oxidation state of Mn} + \text{Total oxidation state of O} = 0 \] \[ +1 + x - 8 = 0 \] where \(x\) is the oxidation state of Mn. 3. **Solve for x:** \[ +1 + x - 8 = 0 \implies x - 7 = 0 \implies x = +7 \] ### Step 2: Determine the oxidation number of Ni in Ni(CO)4 1. **Identify the oxidation states of other elements:** - Carbonyl (CO) is a neutral ligand, thus has an oxidation state of 0. 2. **Set up the equation:** \[ \text{Oxidation state of Ni} + 4 \times \text{Oxidation state of CO} = 0 \] \[ x + 4 \times 0 = 0 \] where \(x\) is the oxidation state of Ni. 3. **Solve for x:** \[ x = 0 \] ### Step 3: Determine the oxidation number of Pt in [Pt(NH3)Cl2]Cl 1. **Identify the oxidation states of other elements:** - Ammonia (NH3) is a neutral ligand, thus has an oxidation state of 0. - Each chloride (Cl) has an oxidation state of -1. Since there are 3 chloride ions, the total contribution from Cl is \(3 \times (-1) = -3\). 2. **Set up the equation:** \[ \text{Oxidation state of Pt} + 0 + 2 \times (-1) = 0 \] \[ x - 2 = 0 \] where \(x\) is the oxidation state of Pt. 3. **Solve for x:** \[ x = +2 \] ### Step 4: Determine the oxidation number of O in Na2O2 1. **Identify the oxidation states of other elements:** - Sodium (Na) has an oxidation state of +1. Since there are 2 sodium atoms, the total contribution from Na is \(2 \times (+1) = +2\). 2. **Set up the equation:** \[ 2 \times \text{Oxidation state of Na} + 2 \times \text{Oxidation state of O} = 0 \] \[ 2 + 2y = 0 \] where \(y\) is the oxidation state of O. 3. **Solve for y:** \[ 2y = -2 \implies y = -1 \] ### Summary of Oxidation Numbers: - A: Mn in KMnO4 = +7 - B: Ni in Ni(CO)4 = 0 - C: Pt in [Pt(NH3)Cl2]Cl = +2 - D: O in Na2O2 = -1 ### Final Answer: The correct code for the oxidation numbers of the asterisked atoms is: - A: 1 (Mn = +7) - B: 2 (Ni = 0) - C: 3 (Pt = +2) - D: 4 (O = -1) Thus, the final answer is **2 3 1 4**.
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{:("Compound",,,,"Total stereoisomer"),((A)[Co(en)_(2)Cl]^(+),,,,(P)2),((B)[Co(en)_(3)]Cl_(3),,,,(Q)3),((C)[Pt(NH_(3))_(2)Cl_(2)],,,,(R)4),((D)[Pt(NH_(3))_(3)Cl_(3)]^(+),,,,(S)5):} Correct code :-

Among [Ni(CO)_(4)], [NiCl_(4)]^(2-), [Co (NH_(3))_(4) Cl_(2)] Cl, Na_(3) [CoF_(6)], Na_(2)O_(2) and CsO_(2) , the total number of paramagnetic compounds is

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FeCr_(2)O_(4)+Na_(2)CO_(3)+O_(2) to Fe_(2)O_(3)darr+Na_(2)CrO_(4)

2AgNO_(3)+Na_(2)C_(2)O_(4) to Ag_(2)C_(2)O_(4)darr+2NaNO_(3)

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(a) Name the types of isomerrism shown by the following pairs of compounds: (i) [CoCl(H_(2)O)(NH_(3))_(4)]Cl_(2) and [CoCl_(2)(NH_(3))_(4)]Cl.H_(2)O (ii) [Pt(NH_(3))_(4)]PtCl_(6)] and [Pt(NH_(3))_(4)Cl_(2)][PtCl_(4)] . (b) Write the IUPAC name of [Co(en)_(2)Cl_(2)]^(+) ion and draw the structure of its geometrical isomers.

The correct IUPAC name of [Pt(NH_(3))_(2)Cl_(4)] is

Write the oxyacids of the following {:("Oxide","Oxyacids"),(N_(2)O_(3),),(NO_(2)//N_(2)O_(4),),(N_(2)O_(5),),(P_(4)O_(6),),(P_(4)O_(10),):}

In [Cr(O_(2))(NH_(3))_(4)H_(2)O]Cl_(2) oxidation number of Cr is +3 then oxygen will be the form:

ALLEN-REDOX REACTIONS-Exercise - 1
  1. Oxidation number of sulphur in Na(2)S(2)O(3) is

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  2. Two oxidation states for chlorine are found in the compound :

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  3. {:(,"Compounds",,"O.N."),((A),KMn^(**)O(4),(1),+4),((B),Ni^(**)(CO)(4)...

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  4. -1//3 oxidation state of nitrogen will be obtained in case of :

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  5. Find the oxidation number of Fe in Fe(3)O(4)

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  6. Compound YBa(2)Cu(3)O(7) is a super conductor The O.N. of the copper i...

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  7. Which one of the following is a redox reaction ?

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  8. Which of the following is not a redox reaction ?

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  9. In the context of the reaction, 4Fe+3O(2)rarr4Fe^(3+)+6O^(2-) , whic...

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  10. In the reaction :Cl(2)+OH^(-)rarrCl^(-)+ClO(4)^(-)+H(2)O

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  11. Which is a redox reaction :

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  12. Which of the following examples does not represent disproportionation ...

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  13. The decomposition of KClO(3) to KCl and O(2) on heating is an example ...

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  14. Which of the following changes represent a disproportionation reaction...

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  15. One mole on iron [55.8 gm], when oxidised to +2 oxidation state gives ...

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  16. How many electrons should X(2)H(4) liberate so that in the new compoun...

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  17. A reducing agent is a substance which can

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  18. The reaction H(2)S+H(2)O(2)toS+2H(2)Omanifests

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  19. If an element is in its lowest oxidation state, under proper condition...

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  20. In a reaction H(2)O("steam")+C("glowing") to CO+H(2)

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