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Assertion :- Oxidation state of Hydrogen...

Assertion :- Oxidation state of Hydrogen is `+1` in `H_(2)O` while `-1` in `CaH_(2)`.
Reason :- `CaH_(2)` is a metal hydride and for metal hydrides, hydrogen is assigned the oxidation number of `-1`.

A

If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.

B

If both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.

C

If Assertion is True but the Reason is False.

D

If both Assertion & Reason are False.

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AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Analyze the Assertion The assertion states that the oxidation state of hydrogen is +1 in H₂O and -1 in CaH₂. 1. **Calculate the oxidation state of hydrogen in H₂O:** - In H₂O, we have 2 hydrogen atoms and 1 oxygen atom. - Let the oxidation state of hydrogen be \( x \). - The oxidation state of oxygen is typically -2. - The equation can be set up as: \[ 2x + (-2) = 0 \] - Solving for \( x \): \[ 2x - 2 = 0 \\ 2x = 2 \\ x = +1 \] - Therefore, the oxidation state of hydrogen in H₂O is +1. 2. **Calculate the oxidation state of hydrogen in CaH₂:** - In CaH₂, we have 2 hydrogen atoms and 1 calcium atom. - Let the oxidation state of hydrogen be \( y \). - The oxidation state of calcium is +2. - The equation can be set up as: \[ 2y + (+2) = 0 \] - Solving for \( y \): \[ 2y + 2 = 0 \\ 2y = -2 \\ y = -1 \] - Therefore, the oxidation state of hydrogen in CaH₂ is -1. ### Conclusion for Assertion The assertion is true: the oxidation state of hydrogen is +1 in H₂O and -1 in CaH₂. ### Step 2: Analyze the Reason The reason states that CaH₂ is a metal hydride and for metal hydrides, hydrogen is assigned an oxidation number of -1. 1. **Understanding Metal Hydrides:** - Metal hydrides are compounds formed between metals and hydrogen. - In these compounds, hydrogen typically has an oxidation state of -1. 2. **Check the validity of the reason:** - Since CaH₂ is indeed a metal hydride (calcium being a metal), the statement that hydrogen has an oxidation number of -1 in metal hydrides is correct. ### Conclusion for Reason The reason is also true: CaH₂ is a metal hydride, and in such compounds, hydrogen is assigned an oxidation number of -1. ### Final Conclusion Both the assertion and the reason are true, and the reason correctly explains the assertion. ### Answer The correct answer is: **Both the assertion and reason are true, and the reason is the correct explanation of the assertion.**
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