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Assertion :- Bromide ion is serving as a...

Assertion :- Bromide ion is serving as a reducing agent in the reaction
`2MnO_(4)^(-)(aq.)+Br^(-)(aq.)+H_(2)Orarr2MnO_(2)(aq.)+BrO_(3)^(-)(aq.)+2OH^(-)(aq.)`
Reason :- Oxidation number of Br increases from `-1` to `+5`

A

If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.

B

If both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.

C

If Assertion is True but the Reason is False.

D

If both Assertion & Reason are False.

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the assertion and reason provided in the question, we will break down the redox reaction step by step. ### Step-by-Step Solution: 1. **Identify the Reaction**: The given reaction is: \[ 2MnO_4^-(aq) + Br^-(aq) + H_2O \rightarrow 2MnO_2(aq) + BrO_3^-(aq) + 2OH^-(aq) \] 2. **Determine Oxidation States**: - For the bromide ion \( Br^- \), the oxidation state is \(-1\). - In the bromate ion \( BrO_3^- \), let the oxidation state of bromine be \( x \). The oxidation states of oxygen is \(-2\). The equation for the oxidation state can be set up as: \[ x + 3(-2) = -1 \implies x - 6 = -1 \implies x = +5 \] - Thus, the oxidation state of bromine in \( BrO_3^- \) is \( +5 \). 3. **Analyze the Change in Oxidation State**: - The oxidation state of bromine changes from \(-1\) (in \( Br^- \)) to \( +5 \) (in \( BrO_3^- \)). - This indicates that bromine is being oxidized, as its oxidation state is increasing. 4. **Identify the Role of Bromide Ion**: - A reducing agent is a substance that donates electrons and gets oxidized in a chemical reaction. Since bromine goes from \(-1\) to \( +5\), it is losing electrons and thus acting as a reducing agent. 5. **Examine the Manganese Species**: - In the reaction, manganese in \( MnO_4^- \) has an oxidation state of \( +7 \) and in \( MnO_2 \), it has an oxidation state of \( +4 \). - This indicates that manganese is being reduced (gaining electrons) as its oxidation state decreases from \( +7 \) to \( +4 \). 6. **Conclusion**: - Since bromide ion \( Br^- \) is being oxidized (its oxidation state increases from \(-1\) to \( +5\)), it is indeed serving as a reducing agent. - Therefore, both the assertion and the reason are correct, and the reason correctly explains the assertion. ### Final Answer: Both the assertion and reason are correct, and the reason is the correct explanation of the assertion.
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