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Assertion :- In acidic medium, equivalen...

Assertion :- In acidic medium, equivalent weight of `K_(2)Cr_(2)O_(7)` is equal to `294//6`.
Reason :- In acidic medium, `Cr_(2)O_(7)^(-2)` is reduced in `Cr^(+3)`

A

If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.

B

If both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.

C

If Assertion is True but the Reason is False.

D

If both Assertion & Reason are False.

Text Solution

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The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understanding the Assertion The assertion states that in acidic medium, the equivalent weight of potassium dichromate (K₂Cr₂O₇) is equal to \( \frac{294}{6} \). - **Molecular Weight Calculation**: The molecular weight of K₂Cr₂O₇ is given as 294 g/mol. - **Equivalent Weight Formula**: The equivalent weight of a substance can be calculated using the formula: \[ \text{Equivalent Weight} = \frac{\text{Molecular Weight}}{n} \] where \( n \) is the number of electrons transferred in the redox reaction. ### Step 2: Understanding the Reason The reason states that in acidic medium, \( \text{Cr}_2\text{O}_7^{2-} \) is reduced to \( \text{Cr}^{3+} \). - **Redox Reaction**: The reduction of dichromate ion can be represented as follows: \[ \text{Cr}_2\text{O}_7^{2-} + 14\text{H}^+ + 6\text{e}^- \rightarrow 2\text{Cr}^{3+} + 7\text{H}_2\text{O} \] Here, each chromium atom in \( \text{Cr}_2\text{O}_7^{2-} \) is reduced from an oxidation state of +6 to +3, which involves a total transfer of 6 electrons. ### Step 3: Calculating the Equivalent Weight Now, we can calculate the equivalent weight using the information gathered: 1. **Molecular Weight of K₂Cr₂O₇**: 294 g/mol 2. **n Factor**: From the balanced redox reaction, we see that 6 electrons are transferred. 3. **Equivalent Weight Calculation**: \[ \text{Equivalent Weight} = \frac{294 \text{ g/mol}}{6} = 49 \text{ g/equiv} \] ### Conclusion Both the assertion and the reason are correct: - The assertion that the equivalent weight of K₂Cr₂O₇ in acidic medium is \( \frac{294}{6} \) is true. - The reason that \( \text{Cr}_2\text{O}_7^{2-} \) is reduced to \( \text{Cr}^{3+} \) is also true. Thus, the correct answer is that both the assertion and reason are true, and the reason correctly explains the assertion.
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  8. Assertion :- In acidic medium, equivalent weight of K(2)Cr(2)O(7) is e...

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  12. Assertion :- Oxidation number of S in HSO(3)^(-) is +4. Reason :- Su...

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  13. Assertion :- Oxidation number of Carbon in all it's compounds is +4. ...

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