Home
Class 12
CHEMISTRY
Asserton :- KClO(3)rarrKClO(4)+KCl Thi...

Asserton :- `KClO_(3)rarrKClO_(4)+KCl`
This is a disporportionation type reaction.
Reason :- The reaction in which one substance oxidise or reduce is known as disproportionation reaction.

A

If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.

B

If both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.

C

If Assertion is True but the Reason is False.

D

If both Assertion & Reason are False.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason about the reaction \( KClO_3 \rightarrow KClO_4 + KCl \), we will analyze the reaction step by step. ### Step 1: Identify the Assertion and Reason - **Assertion**: The reaction \( KClO_3 \rightarrow KClO_4 + KCl \) is a disproportionation type reaction. - **Reason**: A reaction in which one substance oxidizes and reduces itself is known as a disproportionation reaction. ### Step 2: Understand Disproportionation Reactions A disproportionation reaction is a specific type of redox reaction where a single substance is both oxidized and reduced, resulting in two different products. ### Step 3: Determine the Oxidation States To confirm whether the reaction is a disproportionation reaction, we need to find the oxidation states of chlorine in the reactant and products. 1. **In \( KClO_3 \)**: - Potassium (K) has an oxidation state of +1. - Oxygen (O) has an oxidation state of -2. - Let the oxidation state of Cl be \( x \). - The equation for the oxidation state is: \[ +1 + x + 3(-2) = 0 \implies +1 + x - 6 = 0 \implies x = +5 \] - Therefore, the oxidation state of Cl in \( KClO_3 \) is +5. 2. **In \( KClO_4 \)**: - Potassium (K) has an oxidation state of +1. - Let the oxidation state of Cl be \( y \). - The equation for the oxidation state is: \[ +1 + y + 4(-2) = 0 \implies +1 + y - 8 = 0 \implies y = +7 \] - Therefore, the oxidation state of Cl in \( KClO_4 \) is +7. 3. **In \( KCl \)**: - Potassium (K) has an oxidation state of +1. - Let the oxidation state of Cl be \( z \). - The equation for the oxidation state is: \[ +1 + z = 0 \implies z = -1 \] - Therefore, the oxidation state of Cl in \( KCl \) is -1. ### Step 4: Analyze the Changes in Oxidation States - In \( KClO_3 \), Cl is at +5. - In \( KClO_4 \), Cl is at +7 (oxidation). - In \( KCl \), Cl is at -1 (reduction). This shows that the same element (Cl) is undergoing both oxidation (from +5 to +7) and reduction (from +5 to -1). ### Step 5: Conclusion Since chlorine in \( KClO_3 \) is both oxidized and reduced in the reaction, we conclude that the assertion is correct: the reaction is indeed a disproportionation reaction. However, the reason provided is not entirely accurate because it does not specify that the same substance must undergo both oxidation and reduction. ### Final Answer - **Assertion**: True - **Reason**: False - Therefore, the correct option is **C**: Assertion is true, but the reason is false.
Promotional Banner

Topper's Solved these Questions

  • REDOX REACTIONS

    ALLEN|Exercise EXERICSE - 3|30 Videos
  • Redox Reaction

    ALLEN|Exercise All Questions|19 Videos
  • s-Block element

    ALLEN|Exercise All Questions|14 Videos

Similar Questions

Explore conceptually related problems

Which is not a disproportionation reaction :

Which of the following is a disproportionation reaction?

Which of the following is not a disproportionation reaction ?

Which of the following is not a disproportionation reaction ?

Which of the following reactions are disproportionation reaction ?

Which of the following is/are disproportionation reactions ?

Which of the following is // are disproportionation reactions?

Give the disproportionation reaction of H_3PO_3 .

Which of the following change represents a disproportionation reaction (s) :

Which of the following is not an example of disproportionation reaction ?

ALLEN-REDOX REACTIONS-EXERICSE - 4
  1. Assertion :- Oxidation state of Hydrogen is +1 in H(2)O while -1 in Ca...

    Text Solution

    |

  2. Assertion :- Oxidation number of carbon in CH(2)O is zero. Reason :-...

    Text Solution

    |

  3. Assertion :- Nitrous acid (HNO(2)) may act as an oxidising agent as we...

    Text Solution

    |

  4. Assertion :- Oxidation number of Ni in [Ni(CO)(4)] is zero. Reason :-...

    Text Solution

    |

  5. Assertion :- A reducing agent is a substance which accepts electron. ...

    Text Solution

    |

  6. Assertion :- Bromide ion is serving as a reducing agent in the reactio...

    Text Solution

    |

  7. Statement 1: Equivalent weight of NH3 in the reaction N(2) + H(2) to N...

    Text Solution

    |

  8. Assertion :- In acidic medium, equivalent weight of K(2)Cr(2)O(7) is e...

    Text Solution

    |

  9. Assertion :- In a redox reaction, the oxidation number of the oxidant ...

    Text Solution

    |

  10. STATEMENT-1 : H(2)SO(4) can not act as reducing agent. STATEMENT-2 :...

    Text Solution

    |

  11. Assertion :- In HClO(4), Chlorine has the oxidation number of +4. Re...

    Text Solution

    |

  12. Assertion :- Oxidation number of S in HSO(3)^(-) is +4. Reason :- Su...

    Text Solution

    |

  13. Assertion :- Oxidation number of Carbon in all it's compounds is +4. ...

    Text Solution

    |

  14. Assertion :- H(2) is the reducing agent and Cl(2) is reduced in the re...

    Text Solution

    |

  15. Assertion :- MnO(4)^(-) is always reduced to Mn^(+2). Reason :- Decr...

    Text Solution

    |

  16. Asserton :- KClO(3)rarrKClO(4)+KCl This is a disporportionation type...

    Text Solution

    |

  17. Assertion :- Oxidation number of Cr in CrO(3) is +6. Reason :- In Cr...

    Text Solution

    |

  18. Assertion :- Oxidation number of Cr in Cr(CO)(6) is zero. Reason :- ...

    Text Solution

    |

  19. Assertion :- Cr^(+2) is a reducing agent and Mn^(+3) is oxidising agen...

    Text Solution

    |

  20. Asserton :- The formal oxidation no. of sulphur in Na(2)S(4)O(6) is 2....

    Text Solution

    |