Home
Class 12
CHEMISTRY
The spontaneous nature of a reaction is ...

The spontaneous nature of a reaction is impossible if

A

`Delta H` is `+ve, Delta S` is also + ve

B

`Delta H` is `-ve, Delta S` is also - ve

C

`Delta H` is `- ve , Delta S` is + ve

D

`Delta H` is `+ve , Delta S` is -ve

Text Solution

Verified by Experts

The correct Answer is:
D
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    ALLEN|Exercise EXERCISE -3|108 Videos
  • THERMODYNAMICS

    ALLEN|Exercise EXERCISE -4|18 Videos
  • THERMODYNAMICS

    ALLEN|Exercise EXERCISE -1B|22 Videos
  • TEST PAPERS

    ALLEN|Exercise MATHEMATICS|2 Videos
  • Thermodynamics And Thermo Chemistry

    ALLEN|Exercise All Questions|40 Videos

Similar Questions

Explore conceptually related problems

The occurrence of a reaction is impossible if

The force responsible for the spontaneity of a reaction is called ......

A reaction occurs spontaneously in forward direction if

A reaction will never the spontaneous at any temperature and pressure if

Free enegry , G = H - TS , is state function that indicates whther a reaction is spontaneous or non-spontaneous. If you think of TS as the part of the system's enegry that is disordered already, then (H -TS) is the part of the system's energy that is still ordered and therefore free to cause spontaneous change by becoming disordered. Also, DeltaG = DeltaH - T DeltaS From the second law of thermodynamics, a reaction is spontaneous if Delta_("total")S is positive, non-spontaneous if Delta_("total")S is negative, and at equilibrium if Delta_('total")S is zero. Since, -T DeltaS = DeltaG and since DeltaG and DeltaS have opposite sings, we can restate the thermodynamic criterion for the spontaneity of a reaction carried out a constant temperature and pressure. IF DeltaG lt 0 , the reaction is spontaneous. If DeltaG gt 0 , the reaction is non-spontaneous. If DeltaG = 0 , the reaction is at equilibrium. Read the above paragraph carefully and answer the following questions based on the above comprehension. For the spontaneity of a reaction, which statement is true?

Which of the following designation is impossible ?

A: All reactions which are exothermic are spontaneous R: All reactions in which entropy increases are spontaneous

A particular reaction at 27^(@)C for which DeltaH gt 0 and DeltaS gt 0 is found to be non-spontaneous. The reaction may proceed spontaneously if

Assertion:Electrolytic cell uses electrical energy to carry non-spontaneous chemical reactions. Reason : Chemical energy of a spontaneous redox reaction can be converted into electrical energy.

ALLEN-THERMODYNAMICS -EXERCISE -2
  1. A gas is allowed to expand reversibly under adiabatic conditions. What...

    Text Solution

    |

  2. For a reaction at 25^(@)C enthalpy change (DeltaH) and entropy change ...

    Text Solution

    |

  3. The spontaneous nature of a reaction is impossible if

    Text Solution

    |

  4. At a certain temperature T, the endothermic reaction A rarr B proceeds...

    Text Solution

    |

  5. If Delta H gt 0 and Delta S gt 0, the reaction proceeds spontaneously ...

    Text Solution

    |

  6. The temperature at which the reaction Ag(2)O(s)to2Ag(s)+(1)/(2)O(2)(...

    Text Solution

    |

  7. The enthalpy change for a given reaction at 298 K is -x cal mol^(-1). ...

    Text Solution

    |

  8. Which of the following is true fo the reacion H(2)O(l)hArr H(2)O(g) at...

    Text Solution

    |

  9. For the reaction Ag(2)O(s) to 2Ag(s)+1/2 O(2)(g) the value of triangle...

    Text Solution

    |

  10. For hypothetical reversible reaction 1//2A(2)(g) +3//2B(2)(g) rarr A...

    Text Solution

    |

  11. For the precipitation of AgCl by Ag^(+) ions and HCl

    Text Solution

    |

  12. What is the sign of Delta G for the process of ice melting at 283 K ?

    Text Solution

    |

  13. What is the free energy change triangleG when 1.0 mole of water at 100...

    Text Solution

    |

  14. A reaction A +B rarr C+D +q is found to have a positive entropy change...

    Text Solution

    |

  15. Equilibrium constant of a reaction is related to :

    Text Solution

    |

  16. van't Hoff equation is

    Text Solution

    |

  17. If G^(@) gt 0 for a reaction then

    Text Solution

    |

  18. The equilibrium constant for a reaction is 10. What will be the value ...

    Text Solution

    |

  19. When the value of entropy is greater then the ability for useful work ...

    Text Solution

    |

  20. The process of evaporation of a liquid is accompanied by

    Text Solution

    |