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At a certain temperature T, the endother...

At a certain temperature T, the endothermic reaction `A rarr B` proceeds almost to completion.The entropy change is :

A

`Delta S = 0`

B

`Delta S lt 0`

C

`Delta S gt 0`

D

Cannot be predicted

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The correct Answer is:
To solve the problem regarding the entropy change of the endothermic reaction \( A \rightarrow B \) that proceeds almost to completion at a certain temperature \( T \), we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Endothermic Reactions**: - In an endothermic reaction, heat is absorbed from the surroundings. This means that the system (the reactants and products involved in the reaction) takes in energy in the form of heat. 2. **Entropy Change Formula**: - The change in entropy (\( \Delta S \)) for a process can be expressed as: \[ \Delta S = \frac{Q}{T} \] where \( Q \) is the heat absorbed by the system and \( T \) is the absolute temperature at which the process occurs. 3. **Heat Absorption**: - Since the reaction is endothermic, the heat \( Q \) absorbed by the system is positive. Therefore, we can conclude that: \[ Q > 0 \] 4. **Calculating Entropy Change**: - Substituting the positive value of \( Q \) into the entropy change formula gives: \[ \Delta S = \frac{Q}{T} > 0 \] This indicates that the change in entropy is positive. 5. **Conclusion**: - Since the entropy change \( \Delta S \) is greater than zero, we can conclude that the entropy of the system increases as the reaction proceeds. ### Final Answer: The entropy change for the endothermic reaction \( A \rightarrow B \) that proceeds almost to completion is positive (\( \Delta S > 0 \)). Therefore, the correct option is **C**.
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ALLEN-THERMODYNAMICS -EXERCISE -2
  1. For a reaction at 25^(@)C enthalpy change (DeltaH) and entropy change ...

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  2. The spontaneous nature of a reaction is impossible if

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  3. At a certain temperature T, the endothermic reaction A rarr B proceeds...

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  4. If Delta H gt 0 and Delta S gt 0, the reaction proceeds spontaneously ...

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  5. The temperature at which the reaction Ag(2)O(s)to2Ag(s)+(1)/(2)O(2)(...

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  6. The enthalpy change for a given reaction at 298 K is -x cal mol^(-1). ...

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  7. Which of the following is true fo the reacion H(2)O(l)hArr H(2)O(g) at...

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  8. For the reaction Ag(2)O(s) to 2Ag(s)+1/2 O(2)(g) the value of triangle...

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  9. For hypothetical reversible reaction 1//2A(2)(g) +3//2B(2)(g) rarr A...

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  10. For the precipitation of AgCl by Ag^(+) ions and HCl

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  11. What is the sign of Delta G for the process of ice melting at 283 K ?

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  12. What is the free energy change triangleG when 1.0 mole of water at 100...

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  13. A reaction A +B rarr C+D +q is found to have a positive entropy change...

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  14. Equilibrium constant of a reaction is related to :

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  15. van't Hoff equation is

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  16. If G^(@) gt 0 for a reaction then

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  17. The equilibrium constant for a reaction is 10. What will be the value ...

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  18. When the value of entropy is greater then the ability for useful work ...

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  19. The process of evaporation of a liquid is accompanied by

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  20. For the process, CO(2)(s) to CO(2)(g)

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