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What is the sign of Delta G for the proc...

What is the sign of `Delta G` for the process of ice melting at 283 K ?

A

`Delta G gt 0`

B

`Delta G = 0`

C

`Delta G lt 0`

D

None of these

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The correct Answer is:
To determine the sign of ΔG (Gibbs free energy change) for the process of ice melting at 283 K, we can follow these steps: ### Step 1: Understand the process The process in question is the melting of ice (solid H2O) into liquid water (H2O). This phase change occurs at a specific temperature known as the melting point. ### Step 2: Identify the melting point The melting point of ice is 273 K. At this temperature, ice and liquid water are in equilibrium. ### Step 3: Analyze the temperature given The temperature given in the question is 283 K, which is above the melting point of ice (273 K). ### Step 4: Apply the Gibbs free energy equation The Gibbs free energy change (ΔG) for a process can be related to the temperature and the enthalpy (ΔH) and entropy (ΔS) changes of the process using the equation: \[ \Delta G = \Delta H - T \Delta S \] ### Step 5: Determine the signs of ΔH and ΔS - For the melting of ice: - ΔH (enthalpy change) is positive because energy is absorbed to break the bonds in the solid state. - ΔS (entropy change) is also positive because the disorder increases when ice melts into liquid water. ### Step 6: Evaluate ΔG at 283 K Since the temperature (283 K) is above the melting point (273 K), the process of melting ice is spontaneous. In this case, ΔG will be negative: - The positive ΔS term (increased disorder) will outweigh the positive ΔH term (energy absorbed) at this temperature. ### Conclusion Therefore, at 283 K, the sign of ΔG for the melting of ice is negative (ΔG < 0). ### Final Answer The sign of ΔG for the process of ice melting at 283 K is negative. ---

To determine the sign of ΔG (Gibbs free energy change) for the process of ice melting at 283 K, we can follow these steps: ### Step 1: Understand the process The process in question is the melting of ice (solid H2O) into liquid water (H2O). This phase change occurs at a specific temperature known as the melting point. ### Step 2: Identify the melting point The melting point of ice is 273 K. At this temperature, ice and liquid water are in equilibrium. ...
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  16. Which of the following reaction is expected never to be spontaneous :-

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