Home
Class 12
CHEMISTRY
Find the heat change in the reaction: ...

Find the heat change in the reaction:
`NH_3(g)+HCI(g) to NH_4CI(s)`
from the following data
`NH_(3)(g)+aq to NH_(3)(aq) triangleH=-8.4KCal`
`HCl(g)+aq to HCl (aq) triangleH=-17.3KCal`
`NH_(3)(aq)+HCl(aq) to NH_(4)Cl(aq) triangleH=-12.5KCal`
`NH_(4)Cl(s) +aq to NH_(4)Cl(aq) triangleH=+3.9Kcal`

A

`-42.1`

B

`-34.3`

C

`+34.3`

D

`+42.1`

Text Solution

Verified by Experts

The correct Answer is:
A

`NH_(3(g))+HCl_((g))rarr NH_(4)Cl_((s)), Delta H = ?`
Desired equation = eq(i) + eq(ii) + eq(iii) - eq(iv)
`Delta H=(-8.4)+(-17.3)+(-12.5)-(3.9)`
`Delta H =-42.1 KCal`
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    ALLEN|Exercise EXERCISE -4|18 Videos
  • THERMODYNAMICS

    ALLEN|Exercise EXERCISE -2|100 Videos
  • TEST PAPERS

    ALLEN|Exercise MATHEMATICS|2 Videos
  • Thermodynamics And Thermo Chemistry

    ALLEN|Exercise All Questions|40 Videos

Similar Questions

Explore conceptually related problems

For the process NH_(3)(g) +HCI(g) rarr NH_(4)Cl(s)

The reaction NH_(4)^(+)+CN rarr HCN(aq)+NH_(3)(aq) proceeds in

What is the Lewis acid and base in the following reaction? 2NH_(3) (aq) + Ag^(+) (aq) to [Ag(NH_(3))_(2)]^(+) (aq) .

In the reaction 2Al(s)+6HCl(aq)to6Cl^(-)(aq)+3H_2

Calculate the heat of formation of anhydrous Al_2Cl_6 from the following data: (i) 2Al + 6HCl (aq) to Al_2Cl_6 (aq) + 3H_2(g), DeltaH = - 239.76 kcal (ii) Al_2Cl_6 (s) + aq to Al_2Cl_6(aq), DeltaH = - 153.69 kcal (iii) H_2(g) + Cl_2(g) to 2HCl (g) , DeltaH = -44kcal (iv) HCl (g) + aq to HCl (aq), DeltaH = - 17.31 kcal

Which of the following ions dissolve in excess of aq. NH_(3)

The reaction: BaCl_2(aq) + H_2SO_4 (aq) to BaSO_4(s) + 2HCl(aq) is

Identify the oxidant and the reductant respectively in the following reaction. Cl_(2)(g) + 2Br^(-)(aq) to 2Cl^(-)(aq) + Br_(2)(aq)

0.01 M NH_(4)Cl (aq) solution at 25^(@)C has:

The reagents NH_(4)Cl and NH_(3) will precipitate :

ALLEN-THERMODYNAMICS -EXERCISE -3
  1. Given that {:(A(s) rarr A(I)," ",Delta H = x),(A(I) rarr A(g)," ...

    Text Solution

    |

  2. The enthalpy change of a reaction does not depend on

    Text Solution

    |

  3. Form the thermochemical reactions. C(graphite) +1//2 O(2)(g) to CO(g...

    Text Solution

    |

  4. If H(2)+1//2O(2)rarr H(2)O , Delta =-68.39 Kcal K+H(2)O+ "water" rar...

    Text Solution

    |

  5. Given C(s)+O(2)(g)rarr CO(2)(g)+94.2 Kcal H(2)(g)+2O(2)(g)rarr CO(2)...

    Text Solution

    |

  6. From the following data, the heat of formation of Ca(OH)(2)(s) at 18^(...

    Text Solution

    |

  7. If H(2)(g) + Cl(2)(g) rarr 2HCl, Delta H^(@) = -44 kcal" "…..(i) ...

    Text Solution

    |

  8. In the reaction : S+3//2O(2) rarr SO(3)+"2x kcal" and SO(2) +1//2O(2) ...

    Text Solution

    |

  9. If S+O(2)toSO(2),DeltaH=-298.2 " kJ" " mole"^(-1) SO(2)+(1)/(2)O(2)t...

    Text Solution

    |

  10. Givecn that : Zn+1//2O(2)rarr ZnO+84000 cal ……………1 Hg+1//2O(2)rarr...

    Text Solution

    |

  11. Given that - 2C(s)+2O(2)(g)rarr 2CO(2)(g) Delta H = -787 KJ H(2)(g...

    Text Solution

    |

  12. Find the heat change in the reaction: NH3(g)+HCI(g) to NH4CI(s) fr...

    Text Solution

    |

  13. The heat of reaction of A+(1)/(2)O(2)rarr AO is -50 K call and AO+...

    Text Solution

    |

  14. C(s)+O(2)(g)rarr CO(2)(g)+94.0 K cal. CO(g)+(1)/(2)O(2)(g)rarr CO(2)...

    Text Solution

    |

  15. Using the following thermochemical data. C(S)+O(2)(g)rarr CO(2)(g), ...

    Text Solution

    |

  16. The enthalpy of vaporization of liquid water using the data : (i) H...

    Text Solution

    |

  17. H(2)(g)+1//2O(2)(g)=H(2)O(l) , Delta H(298 K)=-68.32 Kcal. Heat of vap...

    Text Solution

    |

  18. The heat of solution of anhydrous CuSO4 and CuSO4. 5H(2)O are -15.89 a...

    Text Solution

    |

  19. One moles of anhydrous AB dissolves in water and liberates 21.0 J mol^...

    Text Solution

    |

  20. Which of the following expression is true?

    Text Solution

    |