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Assertion :- When a rubber band is stret...

Assertion :- When a rubber band is stretched entropy increases.
Reason :- During expansion entropy increases.

A

If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.

B

If both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.

C

If Assertion is True but the Reason is False.

D

If both Assertion & Reason are false.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason given. ### Step 1: Understand the Assertion The assertion states that "When a rubber band is stretched, entropy increases." - **Analysis**: When a rubber band is stretched, the long polymer chains within the rubber band become more aligned. This alignment reduces the randomness of the molecular arrangement. Since entropy is a measure of disorder or randomness, the stretching of the rubber band leads to a decrease in entropy, not an increase. ### Step 2: Understand the Reason The reason states that "During expansion, entropy increases." - **Analysis**: In general, when a system expands, the molecules have more space to move around, which typically increases the randomness of the system. However, in the specific case of a rubber band being stretched, the alignment of the polymers reduces randomness. Therefore, while the reason may hold true for many systems, it does not apply to the rubber band scenario. ### Step 3: Conclusion Both the assertion and the reason are incorrect in the context of a rubber band being stretched. - **Final Answer**: Therefore, the correct answer is that both the assertion and the reason are false. ### Summary of the Solution: 1. **Assertion**: False - Stretching a rubber band decreases entropy due to increased alignment of polymers. 2. **Reason**: False - While expansion generally increases entropy, in the case of a rubber band, stretching decreases randomness and thus decreases entropy. 3. **Correct Answer**: Both assertion and reason are false. ---
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ALLEN-THERMODYNAMICS -EXERCISE -4
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  2. Assertion :- Absolute value of enthalpy can not be determined. Reaso...

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  4. Assertion :- At constant pressure for the change H(2)O(s)rarr H(2)O(g)...

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  5. Assertion (A): Enthalpy of graphite is lower than that of diamond. R...

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  6. Assertion (A): The enthalpy of formation of gaseous oxygen molecules a...

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  7. Many endothermic reactions that are not spontaneous at room temperatur...

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  8. Assertion (A): Pressure, volume, and temperature are all extensive pro...

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  9. Assertion (A): For a particular reaction, heat of combustion at consta...

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  10. Assertion :- At constant temp 0^(@)C and 1 atm, the change H(2)O(s)rar...

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  11. Assertion : The increase in internal energy (DeltaE) for the vapouriz...

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  12. Assertion : Water in liqiud state is more stable than ice at room temp...

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  13. Assertion :- In an isolated system the entropy increases due to sponta...

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  14. Assertion :- Entropy is always constant for a closed system. Reason ...

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  15. Assertion :- For an isolated system q is zero. Reason :- In an isola...

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  16. Assertion :- Entropy of system increases for a spontaneous reactions. ...

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  17. Assertion :- Catalyst change Gibbs free energy of system. Reason :- ...

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  18. Assertion :- Q("Surr") is zero for adiabatic process Reason :- Final...

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