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Assertion:- Mg^(2+) is smaller atomic si...

Assertion:- `Mg^(2+)` is smaller atomic size then `F^(-)`
Resaon :- `Mg^(2+)` has less number of `e^(-)s` than `F^(-)`

A

If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.

B

If both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.

C

If Assertion is True, but the Reason is False.

D

If both Assertion & Reason are false

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The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that `Mg^(2+)` is smaller in atomic size than `F^(-)`. - To evaluate this, we need to consider the atomic structure of both ions. 2. **Analyzing Magnesium Ion (`Mg^(2+)`)**: - Magnesium (Mg) has an atomic number of 12, which means it has 12 protons and, in its neutral state, 12 electrons. - When magnesium loses two electrons to form `Mg^(2+)`, it has 10 electrons remaining (12 protons - 2 electrons = 10 electrons). 3. **Analyzing Fluoride Ion (`F^(-)`)**: - Fluorine (F) has an atomic number of 9, which means it has 9 protons and, in its neutral state, 9 electrons. - When fluorine gains one electron to form `F^(-)`, it has 10 electrons (9 protons + 1 electron = 10 electrons). 4. **Comparing Electron Configuration**: - Both `Mg^(2+)` and `F^(-)` have the same number of electrons (10 electrons). - However, the number of protons differs: `Mg^(2+)` has 12 protons, while `F^(-)` has 9 protons. 5. **Effective Nuclear Charge**: - The effective nuclear charge is the net positive charge experienced by electrons in an atom. It is calculated as the number of protons minus the shielding effect of inner electrons. - In `Mg^(2+)`, the 10 electrons are attracted by 12 protons, leading to a stronger effective nuclear charge. - In `F^(-)`, the 10 electrons are attracted by only 9 protons, resulting in a weaker effective nuclear charge. 6. **Conclusion on Atomic Size**: - Due to the stronger effective nuclear charge in `Mg^(2+)`, the electrons are pulled closer to the nucleus, resulting in a smaller atomic size compared to `F^(-)`. - Therefore, the assertion that `Mg^(2+)` is smaller in atomic size than `F^(-)` is correct. 7. **Evaluating the Reason**: - The reason states that `Mg^(2+)` has fewer electrons than `F^(-)`. This is incorrect because both ions have the same number of electrons (10). - Thus, the reason is false. 8. **Final Answer**: - The assertion is true, but the reason is false. Therefore, the correct answer is option C: Assertion true, reason false.
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