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Pauling.s electronegativity scale is bas...

Pauling.s electronegativity scale is based on experimental value of:-

A

atomic radii

B

bond energies

C

bond lengths

D

electron affinity

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To solve the question regarding Pauling's electronegativity scale, we will follow these steps: ### Step 1: Understand Electronegativity Electronegativity is a measure of the tendency of an atom to attract a bonding pair of electrons. Different elements have different electronegativities, which can affect how they bond with other elements. **Hint:** Remember that electronegativity is related to how strongly an atom can attract electrons in a bond. ### Step 2: Identify Pauling's Contribution Linus Pauling developed a scale to quantify electronegativity. His scale is based on the concept of bond energies, which are the energies required to break bonds between atoms. **Hint:** Think about how bond strength relates to the ability of an atom to attract electrons. ### Step 3: Analyze the Options The question provides four options: 1. Atomic radii 2. Bond energies 3. Bond lengths 4. Electroaffinity Among these, we need to determine which one Pauling's electronegativity scale is based on. **Hint:** Consider which of these options directly relates to the energy changes involved when bonds are formed or broken. ### Step 4: Focus on Bond Energies Pauling's electronegativity scale specifically uses bond energies to establish a quantitative measure of electronegativity. The formula he proposed involves the bond energies of the two atoms involved in the bond. **Hint:** Recall that bond energies indicate how strong a bond is, which is crucial for determining how much an atom can attract electrons. ### Step 5: Conclusion Based on the analysis, the correct answer is: **Bond Energies (Option 2)** **Final Answer:** Pauling's electronegativity scale is based on experimental values of bond energies. ---
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The correct option with respect to the Pauling electronegativity values of the elements is :

Pauling's electronegativity values for elements are useful in predicting

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Mulliken defined the electronegativity of an atom as the arithmetic mean of its ionisation energy and electron affinity. X_(A)=(1)/(2)(I.P.+E.A.) One more relationship given by him, if the values are given in eV is X_(A)=("Ionisation potential"+ "Electron affinity")/(5.6) When there is pure covalent bond between A-B ((IP)_(A)+(EA)_(A))/(5.6)=((IP)_(B)+(EA)_(B))/(5.6) implies X_(A)=X_(B) Pauling's Electronegativity scale is based on

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Compreshension -I The experimental values of colligative properties of many solutes in solution resembles calculated value of colligative properties. However in same cases, the experimental value of colligative property differ widely than those obtained by calculation. Such experimental values of colligative properties are known as Abnormal values of colligative properties are : (i) Dissociation of solute : It increases the colligative properties. (ii) Association of solute : It decreases the colligative properties e.g. : Dimerisation of acetic acid in benzene If degree of dissociation of an electrolyte A_(2)B_(3) is 25% in a solvent, then

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ALLEN-INORGANIC CHEMISTRY-METALLURGY
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