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In which of the following compound all t...

In which of the following compound all the bond angles are equal :-

A

`SF_(4)`

B

`C Cl_(4)`

C

`CHCl_(3)`

D

`XeF_(6)`

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The correct Answer is:
To determine which of the given compounds has all equal bond angles, we will analyze each compound step by step. ### Step 1: Analyze SF4 (Sulfur Tetrafluoride) 1. **Valence Electrons**: Sulfur has 6 valence electrons, and each fluorine has 7. Therefore, SF4 has a total of 6 + (4 × 7) = 34 valence electrons. 2. **Molecular Geometry**: SF4 has a seesaw shape due to one lone pair on sulfur. The presence of this lone pair causes unequal bond angles because of lone pair-bond pair repulsion being greater than bond pair-bond pair repulsion. 3. **Conclusion**: Bond angles in SF4 are not equal. ### Step 2: Analyze CCl4 (Carbon Tetrachloride) 1. **Valence Electrons**: Carbon has 4 valence electrons and each chlorine has 7. Therefore, CCl4 has a total of 4 + (4 × 7) = 32 valence electrons. 2. **Molecular Geometry**: CCl4 has a tetrahedral shape with no lone pairs. All bond angles are equal at 109.5°. 3. **Conclusion**: Bond angles in CCl4 are equal. ### Step 3: Analyze CHCl3 (Chloroform) 1. **Valence Electrons**: Carbon has 4 valence electrons, hydrogen has 1, and chlorine has 7. Therefore, CHCl3 has a total of 4 + 1 + (3 × 7) = 25 valence electrons. 2. **Molecular Geometry**: CHCl3 has a tetrahedral shape but contains different atoms (H and Cl). The bond angles will not be equal due to the difference in electronegativity and size between H and Cl. 3. **Conclusion**: Bond angles in CHCl3 are not equal. ### Step 4: Analyze XeF6 (Xenon Hexafluoride) 1. **Valence Electrons**: Xenon has 8 valence electrons and each fluorine has 7. Therefore, XeF6 has a total of 8 + (6 × 7) = 50 valence electrons. 2. **Molecular Geometry**: XeF6 has a distorted octahedral shape due to the presence of one lone pair. This distortion leads to unequal bond angles. 3. **Conclusion**: Bond angles in XeF6 are not equal. ### Final Conclusion After analyzing all the compounds, the only compound with all equal bond angles is **CCl4**.

To determine which of the given compounds has all equal bond angles, we will analyze each compound step by step. ### Step 1: Analyze SF4 (Sulfur Tetrafluoride) 1. **Valence Electrons**: Sulfur has 6 valence electrons, and each fluorine has 7. Therefore, SF4 has a total of 6 + (4 × 7) = 34 valence electrons. 2. **Molecular Geometry**: SF4 has a seesaw shape due to one lone pair on sulfur. The presence of this lone pair causes unequal bond angles because of lone pair-bond pair repulsion being greater than bond pair-bond pair repulsion. 3. **Conclusion**: Bond angles in SF4 are not equal. ### Step 2: Analyze CCl4 (Carbon Tetrachloride) ...
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ALLEN-INORGANIC CHEMISTRY-CHEMICAL BONDING
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