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When two A.O. combine they form B.MO & A...

When two A.O. combine they form B.MO & ABMO. During BMO .x. energy is released & during ABMO .y. energy is absorbed. So the correct relation will be :-

A

x = y

B

`x lt y`

C

`y lt x`

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the energy changes that occur when two atomic orbitals (A.O.) combine to form bonding molecular orbitals (B.M.O.) and anti-bonding molecular orbitals (A.B.M.O.). ### Step-by-Step Solution: 1. **Understanding Atomic Orbitals (A.O.)**: - When two atomic orbitals combine, they can form two types of molecular orbitals: bonding molecular orbitals (B.M.O.) and anti-bonding molecular orbitals (A.B.M.O.). - For example, consider two 1s atomic orbitals combining. 2. **Formation of Bonding and Anti-bonding Orbitals**: - The combination of two atomic orbitals results in one bonding molecular orbital (B.M.O.) and one anti-bonding molecular orbital (A.B.M.O.). - The bonding molecular orbital is lower in energy compared to the original atomic orbitals, while the anti-bonding molecular orbital is higher in energy. 3. **Energy Changes During Formation**: - When the bonding molecular orbital is formed, energy (let's denote this as x) is released. This is because the system moves to a lower energy state. - Conversely, when the anti-bonding molecular orbital is formed, energy (denote this as y) is absorbed. This is because the system moves to a higher energy state. 4. **Applying the Law of Conservation of Energy**: - According to the law of conservation of energy, the energy released during the formation of the bonding molecular orbital must equal the energy absorbed during the formation of the anti-bonding molecular orbital. - Therefore, we can establish the relationship: \( x = y \). 5. **Conclusion**: - The correct relation between the energies x and y is that they are equal, i.e., \( x = y \). ### Final Answer: The correct relation is \( x = y \). ---
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